Inorg Chem 2021 Jun 7. Epub 2021 Jun 7.
Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, United States.
A new long-lived, visible-light-absorbing homoleptic Cu(I) metal-to-ligand charge transfer (MLCT) photosensitizer, [Cu(dchtmp)]PF (dchtmp = 2,9-dicyclohexyl-3,4,7,8-tetramethyl-1,10-phenanthroline), has been synthesized, structurally characterized, and evaluated in terms of its molecular photophysics, electrochemistry, and electronic structure. Static and time-resolved transient absorption (TA) and photoluminescence (PL) spectroscopy measured on the title compound in CHCl (τ = 2.6 μs, Φ = 5. Read More