Inorg Chem 2021 Apr 18;60(7):4385-4396. Epub 2021 Mar 18.
Department of Chemistry & Biochemistry and Centre for Nanoscience, University of Missouri-St. Louis, One University Boulevard, St. Louis, Missouri 63121-4499, United States.
The five new copper(I) complexes [Cu(μ-Cl)(κ-PCP)] (), [Cu(μ-Br)(κ-PCP)] (), [Cu(μ-I)(κ-PCP)] (), [Cu(μ-CN)(κ-PCP)] (), and [Cu(μ-SCN)(κ-PCP)]·CHCl () bearing a 1,3-bis[(di--butylphosphino)methyl]benzene ligand were synthesized and characterized spectroscopically, and the molecular structures of , , and were determined by single-crystal X-ray diffraction techniques. Structural studies for and revealed their binuclear structures with Cu···Cu separations of 2.609(3) and 2. Read More