62 results match your criteria products 4-np


Degradation of the endocrine-disrupting 4-nonylphenol by ferrate(VI): biodegradability and toxicity evaluation.

Environ Sci Pollut Res Int 2021 Oct 27. Epub 2021 Oct 27.

Course of Civil and Environmental Engineering, Department of System Innovation Engineering, Faculty of Science and Engineering, Iwate University, Ueda 4-3-5, Morioka, 020-8551, Japan.

4-Nonylphenol (4-NP) is an endocrine-disrupting and persistent chemical and is partially degraded in conventional wastewater treatment processes. Ferrate(VI) can be used as an environment-friendly oxidizing agent to mediate 4-NP degradation. Thus, this paper evaluates the biodegradability of 4-NP and its degradation products after the addition of ferrate(VI). Read More

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October 2021

Biosynthesis of Cu/KF/[email protected] nanocomposite and its application as a recyclable nanocatalyst for the synthesis of new Schiff base of benzoxazine derivatives and reduction of organic pollutants.

Mol Divers 2021 Oct 13. Epub 2021 Oct 13.

Research Center for Conservation of Culture Relicst (RCCCR), Research Institute of Cultural Heritage & Tourism, Tehran, Iran.

In this work, we synthesized new Schiff base of benzoxazine derivatives in excellent yields using multicomponent reactions of phthalaldehyde or its derivatives, primary amines, isothiocyanate, 2,4-dihydroxyacetophenone, isopropenylacetylene and methyl or ethyl amine in the presence of catalytic amount of Cu/KF/[email protected] NCs in water at room temperature. Also, the catalytic activity of the green synthesized Cu/KF/[email protected] NCs was evaluated in the reduction in organic pollutants such as 4-nitrophenol (4-NP) in water at mild conditions. The results indicated that the biosynthesized NCs have very high and effective catalytic activity for organic pollutants within few seconds. Read More

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October 2021

CeO quantum dots for highly selective and ultrasensitive fluorescence detection of 4-nitrophenol via the fluorescence resonance energy transfer mechanism.

Spectrochim Acta A Mol Biomol Spectrosc 2021 Dec 27;262:120115. Epub 2021 Jun 27.

College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiahang Road 118, Jiaxing 314001, China. Electronic address:

A rapid and simple fluorescence probe based on CeO quantum dots (QDs) was developed for highly selective and ultrasensitive direct determination of 4-nitrophenol (4-NP). CeO QDs were prepared using the sol-gelmethod with the precursor of Ce(NO)·6HO as a cerium source. The products were characterized through high-resolution electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and Raman spectroscopy. Read More

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December 2021

Fabrication of highly stable platinum organosols over DNA-scaffolds for enriched catalytic and SERS applications.

Dalton Trans 2021 Jun;50(21):7198-7211

Electrochemical Process Engineering (EPE), CSIR-Central Electrochemical Research Institute (CECRI), Karaikudi 630003, Tamil Nadu, India. and Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India.

The use of nanomaterials (NMs) in various applications via multidisciplinary approaches is highly necessary in this era. In this line, the impact of noble metals in organic media for both catalysis and surface-enhanced Raman spectroscopic (SERS) studies is most interesting and also has a wider scope in various fields. Nonetheless, the catalytic reduction of aromatic nitro compounds is difficult with poor solubility in aqueous media, and reduction also is less feasible in the absence of noble metal-based catalysts. Read More

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The development of isomer-specific analysis of branched 4-nonylphenol in food for dietary exposure - a critical review of analytical methods and occurrence in foodstuffs.

Food Addit Contam Part A Chem Anal Control Expo Risk Assess 2021 May 30;38(5):842-855. Epub 2021 Mar 30.

Independent Researcher Formerly with Food Research Laboratory, Centre for Food Safety, Food and Environmental Hygiene Department, Hong Kong, China.

4-Nonylphenol (4-NP) is a para-substituted phenolic compound comprising a straight or branched carbon chain group while branched 4-NP consists of 211 possible structural isomers. NP is recognised as an environmental pollutant and exists ubiquitously in both the environment and in food. 4-NP, especially branched 4-NP, has been shown to have the potential role of endocrine disruptor and xeno-oestrogen. Read More

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OctylPhenol (OP) Alone and in Combination with NonylPhenol (NP) Alters the Structure and the Function of Thyroid Gland of the Lizard Podarcis siculus.

Arch Environ Contam Toxicol 2021 Apr 9;80(3):567-578. Epub 2021 Mar 9.

Department of Biology, University of Naples "Federico II", Naples, Italy.

Different environmental contaminants disturb the thyroid system at many levels. AlkylPhenols (APs), by-products of microbial degradation of AlkylPhenol Polyethoxylates (APEOs), constitute an important class of Endocrine Disrupting Chemicals (EDCs), the two most often used environmental APs being 4-nonylphenol (4-NP) and 4-tert-octylphenol (4-t-OP). The purpose of the present study was to investigate the effects on the thyroid gland of the bioindicator Podarcis siculus of OP alone and in combination with NP. Read More

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A fluorescence strategy for monitoring α-glucosidase activity and screening its inhibitors from Chinese herbal medicines based on Cu nanoclusters with aggregation-induced emission.

Anal Bioanal Chem 2021 Apr 11;413(9):2553-2563. Epub 2021 Feb 11.

Key Laboratory of Life-Organic Analysis of Shandong Province, School of Chemistry and Chemical Engineering, Qufu Normal University, Jining, 272000, Shandong, China.

Herein, the self-assembly of 1-dodecanethiol-capped Cu nanoclusters (DT-Cu NCs) is obtained by annealing of dibenzyl ether solution of nanoclusters. These aggregates are composed of small clusters and emit a high level of aggregation-induced emission (AIE) in water. Based on the quenching effect of 4-nitrophenol (4-NP) on DT-Cu NCs, a fluorescence strategy is developed to monitor α-glucosidase (α-Glu) activity and screen its inhibitors from Chinese herbal medicines. Read More

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Cobalt-modified 2D porous organic polymer for highly efficient electrocatalytic removal of toxic urea and nitrophenol.

Chemosphere 2021 Feb 20;265:129052. Epub 2020 Nov 20.

Department of BioNano Technology, Gachon University, Seongnam, 13120, Republic of Korea. Electronic address:

The urea oxidation reaction (UOR) and nitrophenol reduction are safe and key limiting reactions for sustainable energy conversion and storage. Urea and nitrophenol are abundant in industrial and agricultural wastes, human wastewater, and in the environment. Catalytic oxidative and reductive removal is the most effective process to remove urea and 4-nitrophenol from the environment, necessary to protect human health. Read More

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February 2021

Preparation of Ag/TiO nanocomposites with controlled crystallization and properties as a multifunctional material for SERS and photocatalytic applications.

Spectrochim Acta A Mol Biomol Spectrosc 2020 Dec 5;243:118793. Epub 2020 Aug 5.

Public Experimental Research Center of Xuzhou Medical University, Xuzhou City, Jiangsu 221004, China. Electronic address:

Ag/TiO nanocomposites with controlled crystallization and properties were prepared by a simple solvothermal method. By using the same raw materials with different ratio and reaction conditions, the morphologies and crystallization of nanocomposites can be tuned. The components of the products were analyzed by TEM and XRD methods respectively. Read More

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December 2020

Quantification of chitooligosaccharides by FACE method: Determination of combinatory effects of mouse chitinases.

MethodsX 2020 18;7:100881. Epub 2020 Apr 18.

Department of Chemistry and Life Science, Kogakuin University, Hachioji, Tokyo, Japan.

Fluorophore-assisted carbohydrate electrophoresis (FACE) enables detection and quantification of degradation products from artificial and natural chitin substrates such as 4-NP-(GlcNAc), (GlcNAc) and colloidal chitin. The FACE method has been improved by our group for analysis of chitooligosaccharides in the presence of several buffer systems commonly used in the biochemical evaluation of chitinolytic activities of enzymes at pH 2.0-8. Read More

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Molecular characteristics of kappa-selenocarrageenan and application in green synthesis of silver nanoparticles.

Int J Biol Macromol 2019 Dec 4;141:529-537. Epub 2019 Sep 4.

National R&D Center for Se-rich Agricultural Products Processing Technology, College of Food Science and Engineering, Wuhan Polytechnic University, Wuhan 430023, PR China; School of Food Science, Rutgers University, 65 Dudley Road, New Brunswick, NJ 08901, United States.

Selenium is an essential trace element in human body, and kappa-selenocarrageenan (Se-car) is an organic source of selenium supplement. To further utilize Se-car in food packaging, biotherapy or biosensor, the molecular information of Se-car was characterized here and multi-functional Ag NPs synthesized by Se-car were fabricated. Results of GPC-MALLS, FTIR, potentiometric titration, and intrinsic viscosity showed that Se-car was polymerized by nearly 22 basic units of disaccharide. Read More

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December 2019

Carbon Materials Inhibit Formation of Nitrated Aromatic Products in Treatment of Phenolic Compounds by Thermal Activation of Peroxydisulfate in the Presence of Nitrite.

Environ Sci Technol 2019 Aug 18;53(15):9054-9062. Epub 2019 Jul 18.

State Key Laboratory of Urban Water Resource and Environment , Harbin Institute of Technology , Harbin 150090 , China.

Recent studies have reported that toxic nitrated aromatic products are generated during treatment of phenolic compounds by thermally activated peroxydisulfate (thermal/PDS) in the presence of nitrite (NO). This work explored the potential of carbon materials on controlling the formation of nitrated aromatic products using phenol as a model compound. In the presence of selected carbon materials including diverse carbon nanotubes (CNT) and powdered activated carbon (PAC), the transformation kinetics of phenol was significantly enhanced, primarily attributed to nonradical activation of PDS by carbon materials. Read More

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The complex issue of chemicals and microplastic pollution: A case study in North Pacific lanternfish.

Environ Pollut 2019 May 6;248:1000-1009. Epub 2019 Mar 6.

Department of Ecology and Evolutionary Biology, University of Toronto, Toronto, ON, M5S 3B2, Canada. Electronic address:

Marine plastic debris, including microplastics (<5 mm in size), comprises a suite of chemical ingredients and sorbed chemical contaminants. Thus, microplastics are a potential, and debated, source of anthropogenic chemicals for bioaccumulation and biomagnification. Several studies have investigated the role of microplastics as a vector of contaminants to marine organisms via modeling exercises, laboratory experiments, and field studies. Read More

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Bi-Metal Phosphide NiCoP: An Enhanced Catalyst for the Reduction of 4-Nitrophenol.

Nanomaterials (Basel) 2019 Jan 18;9(1). Epub 2019 Jan 18.

Institute of Fundamental and Frontier Science, University of Electronic Science and Technology of China, Chengdu 610054, China.

Porous phosphide NiCoP composite nanomaterials are successfully synthesized at different Ni/Co ratios (=0, 0.5, 1, and 2) to reduce 4-nitrophenol. The X-ray diffraction and X-ray photoelectron spectroscopy results demonstrate that the products are CoP, NiCoP/CoP, NiCoP, and NiCoP/Ni₂P when the Ni/Co ratio is 0, 0. Read More

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January 2019

Adsorption of phenolic compounds from water by a novel ethylenediamine rosin-based resin: Interaction models and adsorption mechanisms.

Chemosphere 2019 Jan 27;214:821-829. Epub 2018 Sep 27.

Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Guangxi Colleges and Universities Key Laboratory of Food Safety and Pharmaceutical Analytical Chemistry, School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning, 530008, Guangxi, China. Electronic address:

This study describes the adsorption performance of a novel ethylenediamine rosin-based resin (EDAR) for several industrially-important phenolic compounds. Its removal of 4-nitrophenol (4-NP) from water was comparable to or better than many commercial resins, although it was less effective with other phenols (i. e. Read More

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January 2019

Rethinking sulfate radical-based oxidation of nitrophenols: Formation of toxic polynitrophenols, nitrated biphenyls and diphenyl ethers.

J Hazard Mater 2019 01 25;361:152-161. Epub 2018 Aug 25.

Univ Lyon, Université Claude Bernard Lyon 1, CNRS, IRCELYON, F-69626, Villeurbanne, France.

Sulfate radical (SO)-based oxidation of nitrophenols (NPs) have been widely studied; however, formation of potentially more toxic polynitroaromatic intermediates has been overlooked. In this contribution, we systematically investigated the degradation of four NPs by a SO-based oxidation process. Degradation efficiency of NPs followed the order: 2-nitrophenol (2-NP) > 4-nitrophenol (4-NP) > 2,4-dinitrophenol (2,4-DNP) > 2,6-dinitrophenol (2,6-DNP). Read More

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January 2019

Fabrication of a highly sensitive electrochemical sensor based on electropolymerized molecularly imprinted polymer hybrid nanocomposites for the determination of 4-nonylphenol in packaged milk samples.

Anal Biochem 2018 10 22;559:44-50. Epub 2018 Aug 22.

Institute of Quality Standard and Testing Technology for Agro-Products, Chinese Academy of Agricultural Sciences, Key Laboratory of Agrifood Safety and Quality, Ministry of Agriculture of China, Beijing, 100081, PR China. Electronic address:

Herein, an imprinted electrochemical sensor based on graphene-Au nanoparticles incorporated with molecularly imprinted polymer (MIP) was fabricated for determination of 4-nonylphenol (4-NP). Grafted MIP electropolymerized on nanoscale multilayer films electrode was achieved using 4-NP as a template and P-aminothiophenol as a functional monomer. The electrochemical properties of the MIP nanoscale multilayer membrances were characterized and measured by cyclic voltammetry and differential pulse voltammetry techniques; using ferrocyanide/ferricyanide-redox marker. Read More

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October 2018

Interfacial Phenomenon and Nanostructural Enhancements in Palladium Loaded Lanthanum Hydroxide Nanorods for Heterogeneous Catalytic Applications.

Sci Rep 2018 Mar 12;8(1):4354. Epub 2018 Mar 12.

Center for Advanced Materials, Qatar University, Doha, 2713, Qatar.

Hydrogenation and cross-coupling reactions are of great importance for industrial applications and noble metal based catalysts are filling the void since the last few decades. However, the high cost of noble metals and poor recycling performance provides an opportunity for chemists to look for alternate options. Herein, we present the use of Lanthanum hydroxide as support for loading ultra-low amount of Pd for hydrogenation and cross-coupling reactions. Read More

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Silver-Incorporated Mussel-Inspired Polydopamine Coatings on Mesoporous Silica as an Efficient Nanocatalyst and Antimicrobial Agent.

ACS Appl Mater Interfaces 2018 Jan 5;10(2):1792-1801. Epub 2018 Jan 5.

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University , 210009 Nanjing, China.

To tackle severe environmental pollution, a search for materials by economical and eco-friendly preparations is demanding for public health. In this study, a novel in situ method to form silver nanoparticles under mild conditions was developed using biomimetic reducing agents of polydopamine coated on the rodlike mesoporous silica of SBA-15. The synthesized SBA-15/polydopamine (PDA)/Ag nanocomposites were characterized by a combination of physicochemical and electrochemical methods. Read More

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January 2018

Application of a novel mass spectrometric (MS) method to examine exposure to Bisphenol-A and common substitutes in a maternal fetal cohort.

Hum Ecol Risk Assess 2018 30;24(2):331-346. Epub 2017 Oct 30.

Environmental and Occupational Health Sciences Institute, Rutgers University, 170 Frelinghuysen Road, Piscataway, NJ08854, USA.

The use of Bisphenol A (BPA) has widely been replaced in consumer products by analogs BPB, BPE, BPF, BPS, and BPAF. Recent studies have linked these substitutes to similar adverse health outcomes as BPA, including disruption of endocrine pathways in animal and human studies. We designed a novel MS method, developed specifically for this study, to capture the most relevant BPA alternatives, BPB, BPE, BPF, BPS, BPAF and 4-NP in human blood and urine to quantify potential in utero exposures. Read More

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October 2017

Heterologous expression and characterization of three laccases obtained from Pleurotus ostreatus HAUCC 162 for removal of environmental pollutants.

J Hazard Mater 2018 Feb 28;344:499-510. Epub 2017 Oct 28.

Key Laboratory of Molecular Biophysics of MOE, College of Life Science and Technology, Huazhong University of Science and Technology, Wuhan 430074, PR China. Electronic address:

Chlorophenols (CPs), nitrophenols (NPs), and sulfonamide antibiotics (SAs) are three types of environmental pollutants that are of great concern because of their prevalence and toxicity. In this study, three laccase isoenzymes obtained from Pleurotus ostreatus HAUCC 162 were heterologously expressed and characterized with respect to their ability to degrade CPs, NPs, and, SAs. The three recombinant laccases can efficiently degrade the three types of considered pollutants using a laccase-mediator system (LMS). Read More

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February 2018

Morphologically controlled synthesis of ferric oxide nano/micro particles and their catalytic application in dry and wet media: a new approach.

Chem Cent J 2017 May 31;11(1):49. Epub 2017 May 31.

Punjab Bio Energy Project of Punjab Government, University of Agriculture, Faisalabad, 38000, Pakistan.

Morphologically controlled synthesis of ferric oxide nano/micro particles has been carried out by using solvothermal route. Structural characterization displays that the predominant morphologies are porous hollow spheres, microspheres, micro rectangular platelets, octahedral and irregular shaped particles. It is also observed that solvent has significant effect on morphology such as shape and size of the particles. Read More

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Ecotoxicological evaluation of the risk posed by bisphenol A, triclosan, and 4-nonylphenol in coastal waters using early life stages of marine organisms (Isochrysis galbana, Mytilus galloprovincialis, Paracentrotus lividus, and Acartia clausi).

Environ Pollut 2018 Jan 23;232:173-182. Epub 2017 Sep 23.

Estación de Ciencias Mariñas de Toralla (ECIMAT), Universidade de Vigo, Illa de Toralla, 36331 Vigo, Galicia, Spain; Departamento de Ecoloxía e Bioloxía Animal, Universidade de Vigo, Campus Lagoas-Marcosende, 36200 Vigo, Galicia, Spain. Electronic address:

This study assessed the environmental risk on coastal ecosystems posed by three phenolic compounds of special environmental and human health concern used in plastics and household products: bisphenol A (BPA), triclosan (TCS) and 4-nonylphenol (4-NP). These three chemicals are among the organic contaminants most frequently detected in wastewater. The most toxic compound tested was 4-NP, with 10% effective concentration at 11. Read More

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January 2018

The role of nitrite in sulfate radical-based degradation of phenolic compounds: An unexpected nitration process relevant to groundwater remediation by in-situ chemical oxidation (ISCO).

Water Res 2017 10 28;123:249-257. Epub 2017 Jun 28.

Univ Lyon, Université Claude Bernard Lyon 1, CNRS, IRCELYON, F-69626, Villeurbanne, France.

As promising in-situ chemical oxidation (ISCO) technologies, sulfate radical-based advanced oxidation processes (SR-AOPs) are applied in wastewater treatment and groundwater remediation in recent years. In this contribution, we report for the first time that, thermally activated persulfate oxidation of phenol in the presence of nitrite (NO), an anion widely present in natural waters, could lead to the formation of nitrated by-products including 2-nitrophenol (2-NP), 4-nitrophenol (4-NP), 2,4-dinitrophenol (2,4-DNP), and 2,6-dinitrophenol (2,6-DNP). Nitrogen dioxide radical (NO), arising from SO scavenging by NO, was proposed to be involved in the formation of nitrophenols as a nitrating agent. Read More

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October 2017

Fabrication of Highly Stable Metal Oxide Hollow Nanospheres and Their Catalytic Activity toward 4-Nitrophenol Reduction.

ACS Appl Mater Interfaces 2017 May 17;9(21):18207-18214. Epub 2017 May 17.

Ministry Key Laboratory of Oil and Gas Fine Chemicals, College of Chemistry and Chemical Engineering, Xinjiang University , Urumqi 830046, China.

In this paper, hollow nanospheres (HNSs) of metal oxides (NiO, CuO, and NiO/CuO) coated with a porous carbon shell ([email protected]) with good structural stability were successfully prepared on the basis of the nanoscale Kirkendall effect. The formation process was based on a template-free method, and the as-prepared [email protected] are very clean compared with products of the template process. In addition, the results of N adsorption-desorption noted that both the metal oxide HNSs and the coated carbon were mesoporous structures. Read More

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Occurrence and ecological risk assessment of emerging organic chemicals in urban rivers: Guangzhou as a case study in China.

Sci Total Environ 2017 Jul 3;589:46-55. Epub 2017 Mar 3.

State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China. Electronic address:

Urban rivers may receive contamination from various sources including point sources like domestic sewage and nonpoint sources (e.g., runoff), resulting in contamination with various chemicals. Read More

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TEMPO-oxidized bacterial cellulose nanofibers-supported gold nanoparticles with superior catalytic properties.

Carbohydr Polym 2017 Mar 9;160:34-42. Epub 2016 Dec 9.

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Key Laboratory of High Performance Fibers and Products (Ministry of Education), College of Materials Science and Engineering, Donghua University, Shanghai, 201620, PR China. Electronic address:

A novel nanohybrid was successfully fabricated by deposition of gold nanoparticles (AuNPs) onto the surface of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-oxidized bacterial cellulose nanofibers (TOBCNs). The prepared AuNPs/TOBCNs nanohybrids were characterized by UV-vis spectral analysis, XRD, TEM and HRTEM. Their catalytic activity for the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) was estimated by UV-vis spectrometry. Read More

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Green synthesis of palladium nanoparticles mediated by black tea leaves (Camellia sinensis) extract: Catalytic activity in the reduction of 4-nitrophenol and Suzuki-Miyaura coupling reaction under ligand-free conditions.

J Colloid Interface Sci 2017 Jan 15;485:223-231. Epub 2016 Sep 15.

Department of Chemistry, Payame Noor University, Tehran, Iran. Electronic address:

The present study was conducted to synthesize palladium nanoparticles (Pd NPs) through a facile and green route using non-toxic and renewable natural black tea leaves (Camellia sinensis) extract, as the reducing and stabilizing agent. The as-prepared [email protected] NPs catalyst was characterized by UV-vis spectroscopy, X-ray diffraction (XRD), fourier transformed infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS). Read More

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January 2017

Nonmicrobial Nitrophenol Degradation via Peroxygenase Activity of Dehaloperoxidase-Hemoglobin from Amphitrite ornata.

Biochemistry 2016 05 22;55(17):2465-78. Epub 2016 Apr 22.

Department of Chemistry, North Carolina State University , Raleigh, North Carolina , 27695-8204.

The marine hemoglobin dehaloperoxidase (DHP) from Amphitrite ornata was found to catalyze the H2O2-dependent oxidation of nitrophenols, an unprecedented nonmicrobial degradation pathway for nitrophenols by a hemoglobin. Using 4-nitrophenol (4-NP) as a representative substrate, the major monooxygenated product was 4-nitrocatechol (4-NC). Isotope labeling studies confirmed that the O atom incorporated was derived exclusively from H2O2, indicative of a peroxygenase mechanism for 4-NP oxidation. Read More

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Uninterrupted galvanic reaction for scalable and rapid synthesis of metallic and bimetallic sponges/dendrites as efficient catalysts for 4-nitrophenol reduction.

Dalton Trans 2015 Mar;44(9):4215-22

Materials Research Centre, Indian Institute of Science, Bangalore-560012, India.

Here, we demonstrate an uninterrupted galvanic replacement reaction (GRR) for the synthesis of metallic (Ag, Cu and Sn) and bimetallic (Cu-M, M=Ag, Au, Pt and Pd) sponges/dendrites by sacrificing the low reduction potential metals (Mg in our case) in acidic medium. The acidic medium prevents the oxide formation on Mg surface and facilitates the uninterrupted reaction. The morphology of dendritic/spongy structures is controlled by the volume of acid used for this reaction. Read More

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