Inorg Chem 2021 Jun 11. Epub 2021 Jun 11.
Department of Materials Engineering, Purdue University, 205 Gates Road, West Lafayette, Indiana 47906, United States.
The amination of 3,4,5-triamino-1,2,4-triazole with -tosylhydroxylamine yielded the nitrogen-rich 1,3,4,5-tetraamino-1,2,4-triazolium cation as its tosylate salt. Subsequent metathesis reactions produced energetic salts with various energetic anions, including perchlorate, nitrate, nitrotetrazolate, and bistetrazolate diolate. All energetic salts possess relatively high heats of formation, thermal sensitivities, and detonation velocities and pressures. Read More