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Ruthenium-nickel-cobalt alloy nanoparticles embedded in hollow carbon microtubes as a bifunctional mosaic catalyst for overall water splitting.

Authors:
Yanqin Xue Qing Yan Xiaojing Bai Yanyan Xu Xuan Zhang Yiju Li Kai Zhu Ke Ye Jun Yan Dianxue Cao Guiling Wang

J Colloid Interface Sci 2022 Apr 6;612:710-721. Epub 2022 Jan 6.

Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, PR China. Electronic address:

The development of efficient bifunctional catalysts for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is essential for reducing the cost of hydrogen production by water splitting. Herein, hollow microtubes composed of RuNiCo alloy nanoparticles uniformly embedded in the carbon matrix ([email protected]) are prepared through a simple impregnation followed by reduction. Benefiting from the unique mosaic structure and the synergistic effect between Ru and NiCo, [email protected] achieves more exposed active sites and improved reaction kinetics. As a consequence, [email protected] exhibits considerable catalytic activities with the overpotentials of 78 mV for HER and 299 mV for OER at 10 mA cm in 1 M KOH. In addition, [email protected] exhibits excellent stability for up to 30 h in both HER and OER processes at 20 mA cm, which is attributed to the protection of the RuNiCo alloy particles by the carbon layer. Furthermore, the assembled [email protected] || [email protected] overall water splitting system shows a cell voltage of 1.58 V at 10 mA cm. The density functional theory (DFT) calculations indicate that the addition of Ru can optimize the hydrogen adsorption free energy of Ni and Co sites. Finally, a solar panel-driven water splitting device is built, which can realize green and sustainable hydrogen production. The fabrication of [email protected] provides a new way for the preparation of effective alloy nanomaterials for energy storage and conversion.

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http://dx.doi.org/10.1016/j.jcis.2022.01.001DOI Listing
April 2022

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