Photoionization studies of reactive intermediates using synchrotron radiation.

Authors:
John M Dyke
John M Dyke
School of Chemistry

Phys Chem Chem Phys 2019 May;21(18):9106-9136

School of Chemistry, University of Southampton, SO17 1BJ, UK.

Photoionization of reactive intermediates with synchrotron radiation has reached a sufficiently advanced stage of development that it can now contribute to a number of areas in gas-phase chemistry and physics. These include the detection and spectroscopic study of reactive intermediates produced by bimolecular reactions, photolysis, pyrolysis or discharge sources, and the monitoring of reactive intermediates in situ in environments such as flames. This review summarises advances in the study of reactive intermediates with synchrotron radiation using photoelectron spectroscopy (PES) and constant-ionic-state (CIS) methods with angular resolution, and threshold photoelectron spectroscopy (TPES), taking examples mainly from the recent work of the Southampton group. The aim is to focus on the main information to be obtained from the examples considered. As future research in this area also involves photoelectron-photoion coincidence (PEPICO) and threshold photoelectron-photoion coincidence (TPEPICO) spectroscopy, these methods are also described and previous related work on reactive intermediates with these techniques is summarised. The advantages of using PEPICO and TPEPICO to complement and extend TPES and angularly resolved PES and CIS studies on reactive intermediates are highlighted.

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Source
http://dx.doi.org/10.1039/c9cp00623kDOI Listing
May 2019

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References

(Supplied by CrossRef)

2013
Article in Chem. Phys.
Dyke et al.
Chem. Phys. 2006
Article in Phys. Chem. Chem. Phys.
Dyke et al.
Phys. Chem. Chem. Phys. 2005
Article in J. Chem. Phys.
Dyke et al.
J. Chem. Phys. 2000

Eland et al.
1974
Article in Acc. Chem. Res.
Berkowitz et al.
Acc. Chem. Res. 1989
Article in Int. Rev. Sci.: Phys. Chem.
Dyke et al.
Int. Rev. Sci.: Phys. Chem. 1982

Dyke et al.
1979

Cockett et al.
1991
Article in J. Chem. Soc., Faraday Trans. 2
Dyke et al.
J. Chem. Soc., Faraday Trans. 2 1987

Chen et al.
1984

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