Crystal structure of bis-[S-hexyl 3-(4-methyl-benzyl-idene)di-thio-carbazato-κ(2) N (3),S]palladium(II).

Authors:
Ennio Zangrando
Ennio Zangrando
Università di Trieste
professor
Trieste, Trieste | Italy

Acta Crystallogr E Crystallogr Commun 2015 Mar 11;71(Pt 3):m63-4. Epub 2015 Feb 11.

Department of Chemical and Pharmaceutical Sciences, via Giorgieri 1, 34127 Trieste, Italy.

The whole mol-ecule of the title complex, [Pd(C15H21N2S2)2], is generated by twofold rotational symmetry. The palladium(II) atom exhibits a square-planar coordination geometry, and is located on the crystallographic twofold axis that induces a cis configuration of the N,S chelating ligands. In the crystal, mol-ecules stack along the c-axis direction and there are no significant inter-molecular inter-actions present. The structure was refined as an inversion twin with a final BASF parameter of 0.34 (2).

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http://dx.doi.org/10.1107/S2056989015002236DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350759PMC
March 2015
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