Inorg Chem 2012 Mar 17;51(5):2728-30. Epub 2012 Feb 17.
Materials Chemistry, Los Alamos National Laboratory, Mail Stop J514, Los Alamos, New Mexico 87545, USA.
The promotion for hydrogen release from ammonia-borane (AB) was observed in the presence of ZIF-8. Even at concentrations of ZIF-8 as low as 0.25 mol %, a reduction of the onset temperature for dehydrogenation accompanies an increase in both the rate and amount of hydrogen released from AB.