Anal Chim Acta 2008 Apr 6;613(2):207-17. Epub 2008 Mar 6.
Faculty of Commodity Science, The Poznań University of Economics, al. Niepodległości 10, 60-967 Poznań, Poland.
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J Agric Food Chem 2005 Sep;53(18):6988-94
Faculty of Commodity Science, The Poznań University of Economics, al. Niepodległości 10, 60-967 Poznań Poland.
The study demonstrates the application of front face and right angle synchronous fluorescence spectroscopy for the characterization of edible oils. The method enables monitoring of tocopherols, pheophytins, and other fluorescent components in edible oils. Principal component analysis of synchronous fluorescence spectra revealed sample clustering according to the type of oil. Read More
Anal Chim Acta 2007 May 13;592(1):82-90. Epub 2007 Apr 13.
Department of Chemistry, Indian Institute of Technology-Madras, Chennai 600036, India.
Quantitative determination of kerosene fraction present in diesel has been carried out based on excitation emission matrix fluorescence (EEMF) along with parallel factor analysis (PARAFAC) and N-way partial least squares regression (N-PLS). EEMF is a simple, sensitive and nondestructive method suitable for the analysis of multifluorophoric mixtures. Calibration models consisting of varying compositions of diesel and kerosene were constructed and their validation was carried out using leave-one-out cross validation method. Read More
J Dairy Sci 2003 Aug;86(8):2508-15
Food Chemistry, Department of Dairy and Food Science, The Royal Veterinary and Agricultural University, Rolighedsvej 30, DK-1958 Frederiksberg C, Denmark.
The present study demonstrates the use of front-face fluorescence spectroscopy and chemometrics for monitoring light-induced changes in plain yogurt during storage. Fluorescence analysis is suggested as a new rapid method for measuring riboflavin content in yogurt. Fluorescence landscapes with excitation wavelengths from 270 to 550 nm and emission wavelengths in the range 310 to 590 nm were obtained from front-face fluorescence measurements directly on yogurt samples during two storage experiments over a period of 5 wk at 4 degrees C. Read More
Appl Spectrosc 2006 Mar;60(3):330-8
Departamento de Química Analítica, Facultad de Ciencias, Universidad de Extremadura, 06071, Badajoz, España.
A spectrofluorimetric method has been developed for the quantitative determination of mefenamic, flufenamic, and meclofenamic acids in urine samples. The method is based on second-order data multivariate calibration (unfolded partial least squares (unfolded-PLS), multi-way PLS (N-PLS), parallel factor analysis (PARAFAC), self-weighted alternating trilinear decomposition (SWATLD), and bilinear least squares (BLLS)). The analytes were extracted from the urine samples in chloroform prior to the determination. Read More