Publications by authors named "Sergey Sakharov"

3 Publications

  • Page 1 of 1

Single crystals of ferroelectric lithium niobate-tantalate LiNbTaO solid solutions for high-temperature sensor and actuator applications.

Acta Crystallogr B Struct Sci Cryst Eng Mater 2020 Dec 16;76(Pt 6):1071-1076. Epub 2020 Nov 16.

Universität Potsdam, Institut für Physik, Karl Liebknecht Str. 24-25, Potsdam, 14471, Germany.

Ferroelectric LiNbTaO solid solutions with various Nb/Ta ratio were grown from the melt by the Czochralski method. The exact composition of the grown crystals was determined by inductively coupled plasma atomic mass spectrometry. The dependence of the crystal composition on the composition of the initial melt was obtained and explained by a wide separation between the phase boundaries of the liquid and solid phases on the LiNbO-LiTaO phase diagram. Using high-resolution X-ray diffraction, the parameters a and c of a crystal unit cell were determined (LiNbTaO: a = 5.1574 Å and c = 13.8498 Å). Further, the Curie temperature T of the crystals was measured using the differential scanning calorimetry technique. T was found to depend on the composition of the crystals that allowed conditions for the monodomainization of the grown crystals to be defined (LiNbTaO: T = 1102°C; LiNbTaO: T = 794°C). Finally, the velocity of surface acoustic waves was determined by scanning electron microscopy and X-ray diffraction techniques (YZ-cut of a LiNbTaO crystal: V = 3440 m s).
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http://dx.doi.org/10.1107/S2052520620014390DOI Listing
December 2020

Preparation and structures of [6,6]-open difluoromethylene[60]fullerenes: C60(CF2) and C60(CF2)2.

Dalton Trans 2007 Dec(45):5322-8

Chemistry Department, Moscow State University, Moscow 119992, Russia.

Difluoromethylenation of C60 with thermally decomposed CF2ClCO2Na provides novel C60(CF2) and C60(CF2)2 compounds with unique [6,6]-open structures. A theoretical survey of CF2 derivatives of C60 demonstrates that carbon cage opening can be controlled via charging of the molecule and that the thermodynamically preferable structures combine the trend to form open isomers with the compactness of the addition motifs, which results in the formation of windows in the fullerene cage.
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http://dx.doi.org/10.1039/b708167gDOI Listing
December 2007

Synthesis and characterization of difluoromethylene-homo[60]fullerene, C60(CF2).

Chem Commun (Camb) 2007 Jan 18(4):374-6. Epub 2006 Dec 18.

Chemistry Department, Moscow State University, Moscow 119992, Russia.

Refluxing of the o-DCB solution of C60 with CF2ClCOONa and 18-crown-6 leads to formation of C60(CF2)n (n = 1-3); the monoadduct C60(CF2) has been found to consist of the main [6,6]- and minor [5,6]-isomers, both having an open structure.
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http://dx.doi.org/10.1039/b611623jDOI Listing
January 2007