Publications by authors named "Senlong Yu"

2 Publications

  • Page 1 of 1

Enantiomeric Switching of the Circularly Polarized Luminescence Processes in a Hierarchical Biomimetic System by Film Tilting.

ACS Nano 2021 01 4;15(1):1397-1406. Epub 2020 Dec 4.

Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute for Advanced Study and Development of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China.

Circularly polarized luminescence (CPL) switching has attracted great attention due to the potential applications in chiral photonics and electronics. However, the lack of examples to achieve switchable CPL within a single material in the dry solid state hampers the scope of applications. Herein, we demonstrate a crystalline chiral polymer film as a polarizing medium consisting of radially assembled twisted crystallites, where achiral aggregation-induced emissive luminogens (AIEgens) are confined between the twisted crystalline stacks, eventually yielding handedness-switchable CPL by simple film tilting. Hierarchically organized twisted crystallites create the selective reflection activity of the polarizing medium. Upon film tilting, enantiomeric switching is realized by selectively collecting transmitted and reflected CPL components. The confined AIEgens in the crystalline polarizing system show a great enhancement of the luminescence efficiency. Moreover, the approach is general with broadband activity, and various AIEgens could be applied to generate full-color-tunable CPL. Additionally, the rigid and continuous nature of this polarizing system affords enhanced optical stability and facile modulation, developing a general route for designing chiroptical materials.
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http://dx.doi.org/10.1021/acsnano.0c08665DOI Listing
January 2021

Integrating Nano-Cu₂[email protected] into In Situ Polymerized Polyethylene Terephthalate (PET) Fibers with Enhanced Mechanical Properties and Antibacterial Activities.

Polymers (Basel) 2019 Jan 10;11(1). Epub 2019 Jan 10.

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, International Joint Laboratory for Advanced Fiber and Low-dimension Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China.

The approach of in situ polymerization modification has proven to be an effective route for introducing functions for polyester materials. In this work, Cu₂[email protected] nanosheets with excellent dispersity and high antibacterial activity were integrated into in situ polymerized polyethylene terephthalate (PET) fibers, revealing an enhanced mechanical performance in comparison with the PET fibers fabricated directly via a traditional melt blending method. Additionally, such an in situ polymerized PET/Cu₂[email protected] fibers displayed highly enhanced mechanical properties; and great antibacterial activities against multi-types of bacterium, including , and . For the as-obtained two types of PET/Cu₂[email protected] fibers, we have detailed their molecular weight (detailed molecular weight) and dispersibility of nano-Cu₂[email protected] and fibers crystallinity was investigated by Gel chromatography (GPC), Scanning electron microscope (SEM), and X-ray diffractometer (XRD), respectively. The results showed that the aggregation of the nano-Cu₂[email protected] in the resultant PET matrix could be effectively prevented during its in situ polymerization process, hence we attribute its highly enhanced mechanical properties to its superior dispersion of nano-Cu₂[email protected]
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http://dx.doi.org/10.3390/polym11010113DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6401950PMC
January 2019
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