Publications by authors named "Peter J Chupas"

64Publications

Active Reaction Control of Cu Redox State Based on Real-Time Feedback from In Situ Synchrotron Measurements.

J Am Chem Soc 2020 Nov 22;142(44):18758-18762. Epub 2020 Oct 22.

Department of Chemistry, Stony Brook University, 100 Nicholls Road, Stony Brook, New York 11794, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/jacs.0c09418DOI Listing
November 2020

Intrinsic Kinetic Limitations in Substituted Lithium-Layered Transition-Metal Oxide Electrodes.

J Am Chem Soc 2020 Apr 31;142(15):7001-7011. Epub 2020 Mar 31.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, 9700 South Cass Avenue, Lemont, Illinois 60439, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/jacs.9b13551DOI Listing
April 2020

Quantifying Reaction and Rate Heterogeneity in Battery Electrodes in 3D through Operando X-ray Diffraction Computed Tomography.

ACS Appl Mater Interfaces 2019 May 7;11(20):18386-18394. Epub 2019 May 7.

Department of Chemistry , Stony Brook University , 100 Nicolls Rd , Stony Brook , New York 11790 , United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/acsami.9b02173DOI Listing
May 2019

Lithiation Thermodynamics and Kinetics of the TiO (B) Nanoparticles.

J Am Chem Soc 2017 09 12;139(38):13330-13341. Epub 2017 Sep 12.

Department of Chemistry, University of Cambridge , Lensfield Road, Cambridge, CB2 1EW, United Kingdom.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/jacs.7b05228DOI Listing
September 2017

Intergranular Cracking as a Major Cause of Long-Term Capacity Fading of Layered Cathodes.

Nano Lett 2017 06 1;17(6):3452-3457. Epub 2017 Jun 1.

Photon Sciences Directorate, Advanced Photon Source, Argonne National Laboratory , 9700 South Cass Avenue, Argonne, Illinois 60439, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/acs.nanolett.7b00379DOI Listing
June 2017

Polyamorphism in Yb-based metallic glass induced by pressure.

Sci Rep 2017 04 25;7:46762. Epub 2017 Apr 25.

Harbin Institute of Technology, Harbin 150080, China.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1038/srep46762DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5404262PMC
April 2017

Topological Transformation of a Metal-Organic Framework Triggered by Ligand Exchange.

Inorg Chem 2017 Apr 6;56(8):4577-4584. Epub 2017 Apr 6.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory , Argonne, Illinois 60439, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/acs.inorgchem.7b00149DOI Listing
April 2017

Accommodating High Transformation Strains in Battery Electrodes via the Formation of Nanoscale Intermediate Phases: Operando Investigation of Olivine NaFePO.

Nano Lett 2017 03 24;17(3):1696-1702. Epub 2017 Feb 24.

Department of Material Science and Engineering, Massachusetts Institute of Technology , 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/acs.nanolett.6b04971DOI Listing
March 2017

Engineering the Transformation Strain in LiMnyFe1-yPO4 Olivines for Ultrahigh Rate Battery Cathodes.

Nano Lett 2016 Apr 7;16(4):2375-80. Epub 2016 Mar 7.

Department of Material Science and Engineering, Massachusetts Institute of Technology , 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/acs.nanolett.5b05146DOI Listing
April 2016

The Interplay of Al and Mg Speciation in Advanced Mg Battery Electrolyte Solutions.

J Am Chem Soc 2016 Jan 22;138(1):328-37. Epub 2015 Dec 22.

Department of Chemistry, University of Illinois at Urbana-Champaign , Urbana, Illinois 61801, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/jacs.5b10987DOI Listing
January 2016

Microwave-assisted synthesis and electrochemical evaluation of VO2 (B) nanostructures.

Acta Crystallogr B Struct Sci Cryst Eng Mater 2015 Dec 1;71(Pt 6):722-6. Epub 2015 Dec 1.

School of Chemistry, University of Glasgow, Glasgow G12 8QQ, Scotland.

View Article

Download full-text PDF

Source
http://journals.iucr.org/b/issues/2015/06/00/xw5006/xw5006.p
Web Search
http://scripts.iucr.org/cgi-bin/paper?S2052520615021289
Publisher Site
http://dx.doi.org/10.1107/S2052520615021289DOI Listing
December 2015

Oxyanion induced variations in domain structure for amorphous cobalt oxide oxygen evolving catalysts, resolved by X-ray pair distribution function analysis.

Acta Crystallogr B Struct Sci Cryst Eng Mater 2015 Dec 1;71(Pt 6):713-21. Epub 2015 Dec 1.

Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Ave, Lemont, IL 60439, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1107/S2052520615022180DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4669998PMC
December 2015

Lithium Insertion Mechanism in Iron-Based Oxyfluorides with Anionic Vacancies Probed by PDF Analysis.

ChemistryOpen 2015 Aug 25;4(4):443-7. Epub 2015 Jun 25.

Sorbonne Universités, UPMC, Univ. Paris 06, UMR 8234, PHENIX 75005, Paris, France ; CNRS, UMR 8234, PHENIX 75005, Paris, France.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1002/open.201500031DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4603403PMC
August 2015

Prediction and Synthesis of Strain Tolerant RbCuTe Crystals Based on Rotation of One-Dimensional Nano Ribbons within a Three-Dimensional Inorganic Network.

J Am Chem Soc 2015 Sep 27;137(35):11383-90. Epub 2015 Aug 27.

Renewable and Sustainable Energy Institute, University of Colorado , Boulder, Colorado 80309-0027, United States.

View Article

Download full-text PDF

Source
http://pubs.acs.org/doi/10.1021/jacs.5b06182
Publisher Site
http://dx.doi.org/10.1021/jacs.5b06182DOI Listing
September 2015

Best Practices for Operando Battery Experiments: Influences of X-ray Experiment Design on Observed Electrochemical Reactivity.

J Phys Chem Lett 2015 Jun;6(11):2081-5

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/acs.jpclett.5b00891DOI Listing
June 2015

Identifying the Structure of the Intermediate, LiCoPO, Formed during Electrochemical Cycling of LiCoPO.

Chem Mater 2014 Nov 9;26(21):6193-6205. Epub 2014 Oct 9.

Department of Chemistry, University of Cambridge , Lensfield Road, Cambridge, Cambridgeshire CB2 1EW, United Kingdom ; Department of Chemistry, State University of New York at Stony Brook , Stony Brook, New York 11794-3400, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/cm502680wDOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4419286PMC
November 2014

Solvation structure and energetics of electrolytes for multivalent energy storage.

Phys Chem Chem Phys 2014 Oct;16(40):21941-5

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439, USA.

View Article

Download full-text PDF

Source
http://xlink.rsc.org/?DOI=C4CP03015J
Publisher Site
http://dx.doi.org/10.1039/c4cp03015jDOI Listing
October 2014

In situ studies of a platform for metastable inorganic crystal growth and materials discovery.

Proc Natl Acad Sci U S A 2014 Jul 14;111(30):10922-7. Epub 2014 Jul 14.

Materials Science Division,Department of Chemistry, Northwestern University, Evanston, IL 60208

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1073/pnas.1406211111DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4121826PMC
July 2014

Batteries. Capturing metastable structures during high-rate cycling of LiFePO₄ nanoparticle electrodes.

Science 2014 Jun;344(6191):1252817

Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK. Department of Chemistry, Stony Brook University, Stony Brook, NY 11794-3400, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1126/science.1252817DOI Listing
June 2014

Adsorbate-induced structural changes in 1-3 nm platinum nanoparticles.

J Am Chem Soc 2014 Jul 24;136(26):9320-6. Epub 2014 Jun 24.

Energy Systems Division, ‡X-ray Science Division, §Chemical Sciences and Engineering Division, Argonne National Laboratory , Lemont, Illinois 60439, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja4126998DOI Listing
July 2014

Structures of delithiated and degraded LiFeBO(3), and their distinct changes upon electrochemical cycling.

Inorg Chem 2014 Jul 10;53(13):6585-95. Epub 2014 Jun 10.

Chemistry Department, Stony Brook University , Stony Brook, New York 11794, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ic500169gDOI Listing
July 2014

Mesoscale effects in electrochemical conversion: coupling of chemistry to atomic- and nanoscale structure in iron-based electrodes.

J Am Chem Soc 2014 Apr 18;136(17):6211-4. Epub 2014 Apr 18.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory , Argonne, Illinois 60439, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja501854yDOI Listing
April 2014

Transport, phase reactions, and hysteresis of iron fluoride and oxyfluoride conversion electrode materials for lithium batteries.

ACS Appl Mater Interfaces 2014 Jul 8;6(14):10858-69. Epub 2014 Apr 8.

Energy Storage Research Group, Department of Materials Science and Engineering, Rutgers University , North Brunswick, New Jersey 08902, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/am500538bDOI Listing
July 2014

Origin of additional capacities in metal oxide lithium-ion battery electrodes.

Nat Mater 2013 Dec 3;12(12):1130-6. Epub 2013 Nov 3.

Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1038/nmat3784DOI Listing
December 2013

Orientational order-dependent thermal expansion and compressibility of ZrW2O8 and ZrMo2O8.

Phys Chem Chem Phys 2013 Dec 17;15(45):19665-72. Epub 2013 Oct 17.

School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1039/c3cp52876fDOI Listing
December 2013

Highly ordered noncrystalline metallic phase.

Phys Rev Lett 2013 Jul 2;111(1):015502. Epub 2013 Jul 2.

X-Ray Science Division, Argonne National Laboratory, Argonne, Illinois 60439, USA.

View Article

Download full-text PDF

Source
http://thermophysics.ru/pdf_doc/2.pdf
Web Search
http://link.aps.org/doi/10.1103/PhysRevLett.111.015502
Publisher Site
http://dx.doi.org/10.1103/PhysRevLett.111.015502DOI Listing
July 2013

Exploiting high pressures to generate porosity, polymorphism, and lattice expansion in the nonporous molecular framework Zn(CN)2.

J Am Chem Soc 2013 May 14;135(20):7621-8. Epub 2013 May 14.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja4012707DOI Listing
May 2013

Mapping spatially inhomogeneous electrochemical reactions in battery electrodes using high energy X-rays.

Phys Chem Chem Phys 2013 Jun 19;15(22):8466-9. Epub 2013 Apr 19.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1039/c3cp50590aDOI Listing
June 2013

Elucidating the domain structure of the cobalt oxide water splitting catalyst by X-ray pair distribution function analysis.

J Am Chem Soc 2012 Jul 28;134(27):11096-9. Epub 2012 Jun 28.

Chemical Sciences and Engineering Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja303826aDOI Listing
July 2012

Understanding fluxes as media for directed synthesis: in situ local structure of molten potassium polysulfides.

J Am Chem Soc 2012 Jun 29;134(22):9456-63. Epub 2012 May 29.

Materials Science Division, Argonne National Laboratory, Illinois 60439, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja303047eDOI Listing
June 2012

Structural and mechanistic revelations on an iron conversion reaction from pair distribution function analysis.

Angew Chem Int Ed Engl 2012 May 11;51(20):4852-5. Epub 2012 Apr 11.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, IL 60439, USA.

View Article

Download full-text PDF

Source
http://doi.wiley.com/10.1002/anie.201200244
Publisher Site
http://dx.doi.org/10.1002/anie.201200244DOI Listing
May 2012

Chasing changing nanoparticles with time-resolved pair distribution function methods.

J Am Chem Soc 2012 Mar 13;134(11):5036-9. Epub 2012 Mar 13.

European Synchrotron Radiation Facility, 6, Rue Jules Horowitz, BP-220, Grenoble, F-38043, France.

View Article

Download full-text PDF

Source
http://pubs.acs.org/doi/10.1021/ja2114163
Publisher Site
http://dx.doi.org/10.1021/ja2114163DOI Listing
March 2012

A new class of lithium and sodium rechargeable batteries based on selenium and selenium-sulfur as a positive electrode.

J Am Chem Soc 2012 Mar 29;134(10):4505-8. Epub 2012 Feb 29.

Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439, United States.

View Article

Download full-text PDF

Source
http://pubs.acs.org/doi/10.1021/ja211766q
Publisher Site
http://dx.doi.org/10.1021/ja211766qDOI Listing
March 2012

Trapping guests within a nanoporous metal-organic framework through pressure-induced amorphization.

J Am Chem Soc 2011 Nov 31;133(46):18583-5. Epub 2011 Oct 31.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA

View Article

Download full-text PDF

Source
http://pubs.acs.org/doi/abs/10.1021/ja2085096
Publisher Site
http://dx.doi.org/10.1021/ja2085096DOI Listing
November 2011

Dual lithium insertion and conversion mechanisms in a titanium-based mixed-anion nanocomposite.

J Am Chem Soc 2011 Aug 5;133(34):13240-3. Epub 2011 Aug 5.

Chemical Sciences and Engineering Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja204284hDOI Listing
August 2011

Capture of volatile iodine, a gaseous fission product, by zeolitic imidazolate framework-8.

J Am Chem Soc 2011 Aug 26;133(32):12398-401. Epub 2011 Jul 26.

Surface and Interface Sciences Department, Sandia National Laboratories, Albuquerque, New Mexico 87185, United States.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja204757xDOI Listing
August 2011

Combining the pair distribution function and computational methods to understand lithium insertion in Brookite (TiO2).

Inorg Chem 2011 Jul 31;50(13):5855-7. Epub 2011 May 31.

Chemical Sciences and Engineering Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ic2004326DOI Listing
July 2011

Elucidating the structure of surface acid sites on γ-Al2O3.

J Am Chem Soc 2011 Jun 16;133(22):8522-4. Epub 2011 May 16.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA.

View Article

Download full-text PDF

Source
http://pubs.acs.org/doi/abs/10.1021/ja2029574
Publisher Site
http://dx.doi.org/10.1021/ja2029574DOI Listing
June 2011

Pronounced negative thermal expansion from a simple structure: cubic ScF(3).

J Am Chem Soc 2010 Nov;132(44):15496-8

School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja106711vDOI Listing
November 2010

Radioactive iodine capture in silver-containing mordenites through nanoscale silver iodide formation.

J Am Chem Soc 2010 Jul;132(26):8897-9

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja103110yDOI Listing
July 2010

Pressure-induced amorphization and porosity modification in a metal-organic framework.

J Am Chem Soc 2009 Dec;131(48):17546-7

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja908415zDOI Listing
December 2009

Pair distribution function analysis of pressure treated zeolite Na-A.

Chem Commun (Camb) 2009 Jun 19(23):3383-5. Epub 2009 May 19.

School of Chemistry, University of Birmingham, Edgbaston, Birmingham, UKB15 2TT.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1039/b902874aDOI Listing
June 2009

Guest-dependent high pressure phenomena in a nanoporous metal-organic framework material.

J Am Chem Soc 2008 Aug 18;130(32):10524-6. Epub 2008 Jul 18.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Il, 60439, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja804079zDOI Listing
August 2008

Watching nanoparticles grow: the mechanism and kinetics for the formation of TiO2-supported platinum nanoparticles.

J Am Chem Soc 2007 Nov 23;129(45):13822-4. Epub 2007 Oct 23.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA.

View Article

Download full-text PDF

Source
http://pubs.acs.org/doi/abs/10.1021/ja076437p
Publisher Site
http://dx.doi.org/10.1021/ja076437pDOI Listing
November 2007

Porous semiconducting gels and aerogels from chalcogenide clusters.

Science 2007 Jul;317(5837):490-3

Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.

View Article

Download full-text PDF

Source
http://www.sciencemag.org/cgi/doi/10.1126/science.1142535
Publisher Site
http://dx.doi.org/10.1126/science.1142535DOI Listing
July 2007

Pressure enhancement of negative thermal expansion behavior and induced framework softening in zinc cyanide.

J Am Chem Soc 2007 Aug 26;129(33):10090-1. Epub 2007 Jul 26.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja073791eDOI Listing
August 2007

The structure of ferrihydrite, a nanocrystalline material.

Science 2007 Jun 24;316(5832):1726-9. Epub 2007 May 24.

Center for Environmental Molecular Science (CEMS), Stony Brook University, Stony Brook, NY 11794, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1126/science.1142525DOI Listing
June 2007

Direct observation of adsorbed H2-framework interactions in the Prussian Blue analogue MnII3[CoIII(CN)6]2: the relative importance of accessible coordination sites and van der Waals interactions.

Chem Commun (Camb) 2006 Oct 16(38):4013-5. Epub 2006 Aug 16.

X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Il., USA.

View Article

Download full-text PDF

Source
http://xlink.rsc.org/?DOI=b607250j
Publisher Site
http://dx.doi.org/10.1039/b607250jDOI Listing
October 2006

Compositional dependence of negative thermal expansion in the Prussian Blue analogues M(II)Pt(IV)(CN)6 (M = Mn, Fe, Co, Ni, Cu, Zn, Cd).

J Am Chem Soc 2006 May;128(21):7009-14

School of Chemistry, University of Sydney, Sydney, NSW 2006, Australia.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja060916rDOI Listing
May 2006

Direct observation of a transverse vibrational mechanism for negative thermal expansion in Zn(CN)2: an atomic pair distribution function analysis.

J Am Chem Soc 2005 Nov;127(44):15630-6

School of Chemistry, University of Sydney, Sydney, NSW 2006 Australia.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja055197fDOI Listing
November 2005

Quantitative high-pressure pair distribution function analysis.

J Synchrotron Radiat 2005 Sep 16;12(Pt 5):554-9. Epub 2005 Aug 16.

Center for Environmental Molecular Sciences, CEMS, Stony Brook, NY 11794, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1107/S0909049505022612DOI Listing
September 2005

Measuring Brønsted acid densites in zeolite HY with diphosphine molecules and solid state NMR spectroscopy.

J Am Chem Soc 2004 Oct;126(39):12254-5

Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794-3400, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja0467519DOI Listing
October 2004

Probing local and long-range structure simultaneously: an in situ study of the high-temperature phase transition of alpha-AlF3.

J Am Chem Soc 2004 Apr;126(15):4756-7

Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794, USA.

View Article

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja031553nDOI Listing
April 2004