Publications by authors named "Patrick Murmann"

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Lithium-cyclo-difluoromethane-1,1-bis(sulfonyl)imide as a stabilizing electrolyte additive for improved high voltage applications in lithium-ion batteries.

Phys Chem Chem Phys 2015 Apr 11;17(14):9352-8. Epub 2015 Mar 11.

Westfälische Wilhelms-Universität Münster, Institute of Physical Chemistry, MEET Battery Research Center, Corrensstr. 46, 48149 Muenster, Germany.

Lithium-cyclo-difluoromethane-1,1-bis(sulfonyl)imide (LiDMSI) was evaluated as an electrolyte additive in lithium-ion batteries for improved high voltage applications. Cycling the cathode at high potentials leads to the electrochemical oxidation of the salt to form a cathode electrolyte interphase (CEI) layer on the cathode surface. With the addition of 2 wt% of LiDMSI to the 1 M LiPF6 in 1 : 1 (by wt) EC : DEC electrolyte, the capacity retention and the Coulombic efficiency in LiNi1/3Co1/3Mn1/3O2/Li-half-cells as well as in LiNi1/3Co1/3Mn1/3O2/graphite-full-cells were improved. The cycling results point out the less over-potential and resistance at the cathode/electrolyte interface. These improvements are studied by SEM, EIS and XPS techniques.
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http://dx.doi.org/10.1039/c5cp00483gDOI Listing
April 2015
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