Publications by authors named "Nareerat Plylahan"

3 Publications

  • Page 1 of 1

Enhanced electrochemical performance of Lithium-ion batteries by conformal coating of polymer electrolyte.

Nanoscale Res Lett 2014 2;9(1):544. Epub 2014 Oct 2.

Aix-Marseille Université, CNRS, LP3 UMR 7341, F-13288, Marseille Cedex 9, France ; Aix-Marseille Université, CNRS, MADIREL UMR 7246, F-13397, Marseille Cedex 20, France.

This work reports the conformal coating of poly(poly(ethylene glycol) methyl ether methacrylate) (P(MePEGMA)) polymer electrolyte on highly organized titania nanotubes (TiO2nts) fabricated by electrochemical anodization of Ti foil. The conformal coating was achieved by electropolymerization using cyclic voltammetry technique. The characterization of the polymer electrolyte by proton nuclear magnetic resonance ((1)H NMR) and size-exclusion chromatography (SEC) shows the formation of short polymer chains, mainly trimers. X-ray photoelectron spectroscopy (XPS) results confirm the presence of the polymer and LiTFSI salt. The galvanostatic tests at 1C show that the performance of the half cell against metallic Li foil is improved by 33% when TiO2nts are conformally coated with the polymer electrolyte.
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http://dx.doi.org/10.1186/1556-276X-9-544DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4194452PMC
October 2014

Sulfidated TiO2 nanotubes: a potential 3D cathode material for Li-ion micro batteries.

Chem Commun (Camb) 2013 May 20;49(39):4205-7. Epub 2012 Nov 20.

Aix Marseille University, CNRS, LP3 UMR 7341, 13288, Marseille, France.

In this work, self-organized titania nanotubes are sulfidated by an annealing treatment to produce TiOxSy nanotubes. Morphological, structural and electrochemical analyses show that this 3D nanostructured electrode is a potential cathode material for Li-ion microbatteries.
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http://dx.doi.org/10.1039/c2cc36857aDOI Listing
May 2013

Highly conformal electrodeposition of copolymer electrolytes into titania nanotubes for 3D Li-ion batteries.

Nanoscale Res Lett 2012 Jun 27;7(1):349. Epub 2012 Jun 27.

Aix Marseille Université, CNRS, Chemistry of Materials Research Group LP3 UMR 7341, Marseille, F-13288, France.

The highly conformal electrodeposition of a copolymer electrolyte (PMMA-PEO) into self-organized titania nanotubes (TiO2nt) is reported. The morphological analysis carried out by scanning electron microscopy and transmission electron microscopy evidenced the formation of a 3D nanostructure consisting of a copolymer-embedded TiO2nt. The thickness of the copolymer layer can be accurately controlled by monitoring the electropolymerization parameters. X-ray photoelectron spectroscopy measurements confirmed that bis(trifluoromethanesulfone)imide salt was successfully incorporated into the copolymer electrolyte during the deposition process. These results are crucial to fabricate a 3D Li-ion power source at the micrometer scale using TiO2nt as the negative electrode.
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http://dx.doi.org/10.1186/1556-276X-7-349DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3536562PMC
June 2012
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