Najeem O Oladosu, PhD - University of Lagos - Dr.

Najeem O Oladosu

PhD

University of Lagos

Dr.

Akoka, Lagos | Nigeria

Main Specialties: Chemistry

Additional Specialties: Analytical Chemistry (specifically flow injection techniques), Environmental Chemistry (specifically N and P emissions and discharges to air and waters respectively) and Green Chemistry.

ORCID logohttps://orcid.org/0000-0003-0439-9699

Najeem O Oladosu, PhD - University of Lagos - Dr.

Najeem O Oladosu

PhD

Publications

4Publications

236Reads

82Profile Views

Online zinc reduction-sequential injection analysis for the determination of nitrogen species in extracts of riverine sediment

J Anal Sci Technol (2017) 8: 5.

Journal of Analytical Science and Technology

Abstract

Background: The substitution of hazardous analytical reagents such as Cd with benign alternatives for chemical determination is one of the principles of green chemistry. An eco-friendly Zn reduction method for nitrate determination was developed to achieve this end.

Methods: Online zinc reduction-sequential injection analysis (ZnR-SIA) protocol was developed for the determination of nitrogen (N) species in the Lagos Lagoon sediments by modification of some standard methods.

Results: The novel application of boric acid-borate buffer employed in borate-buffered granular Zn reduction suppressed gas evolution from the Zn micro-column, making the Zn reduction adaptable to online use, unlike the frequently used ammonia-ammonium buffer. Further results showed that the sampling rate for the two-zone stack was 65 h−1. The boric acid-borate buffer offered 5.9-fold and 1.3-fold of the instrument response given by the ammonia-ammonium buffer at 0.50 and 5.0 mg N L−1 respectively. The method detection limits of the ZnR-SIA for the three matrices studied were 24.6 μg N L−1 for reagent water, 0.383 mg N kg−1 for KCl-extractable nitrate, and 3.18 mg N kg−1 for total nitrogen. The average recovery of nitrate-N in matrix samples was 94.7%, and its precision was 4.52%. The average recoveries of total N in blanks and matrix samples were 97.9 and 93.2% respectively.

Conclusions: The method accuracies demonstrated the suitability of the ZnR-SIA for sediment N determination. Zn reduction is recommended where sustainable development is desired and is a potential substitute for the standard Cd reduction owing to Cd toxicity.

Keywords: Green chemistry, Sediment nitrogen, Online zinc reduction, Borate buffer, Sequential injection

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April 2017
7 Reads

Wet nitrogen and phosphorus deposition in the eutrophication of the Lagos Lagoon, Nigeria.

Environ Sci Pollut Res Int 2017 Mar 15;24(9):8645-8657. Epub 2017 Feb 15.

Department of Chemistry, University of Lagos, Akoka, Yaba, Lagos, PMB. 1005, Nigeria.

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http://dx.doi.org/10.1007/s11356-017-8479-6DOI Listing
March 2017
3 Reads
2.828 Impact Factor

Assessment of nitrogen and phosphorus loading by atmospheric dry deposition to the Lagos Lagoon, Nigeria.

Environ Monit Assess 2016 Jul 20;188(7):423. Epub 2016 Jun 20.

Department of Chemistry, University of Lagos, Akoka, Lagos, Nigeria.

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http://dx.doi.org/10.1007/s10661-016-5389-xDOI Listing
July 2016
233 Reads
1.679 Impact Factor

Sequential Injection Analysis for the Monitoring of Riverine Phosphorus and Iron Inputs into the Lagos Lagoon Sediments

J. Flow Injection Anal., Vol. 33, No. 1 (2016) 13-21

Journal of Flow Injection Analysis

ABSTRACT

Sequential injection analysis (SIA) protocols for the determination of phosphorus and mineral iron (Fe) in the Lagos Lagoon sediment were developed by optimizing some existing standard methods. Sandwiched sample was found to offer higher sensitivity than a 2-zone stack for P SIA. The injection volumes of sample and reagent for P analysis were 40 µL and 20 µL (split into two 10-µL zones) respectively while 150 µL of sample and 10 µL of reagent were injected in Fe analysis. The sampling rates were 31 h-1 and 75 h-1 for P and Fe SIA protocols respectively. Quantitative digestion of total P was achieved by a sediment-to-persulfate ratio of 1:3 by mass in 2.0 mL of 0.3 M NaOH. Average recovery of bioavailable P in matrix samples was 91.7 % and average recoveries of total P were 111.5 % and 96.6 % in matrix samples and blanks respectively. Average recovery of mineral iron in matrix samples was 94.3 % while average recovery in blanks was 97.4 %. The method detection limits were 1.4 mg P kg-1 and 2.6 mg P kg-1 for bioavailable-P and total-P methods respectively while the method detection limit for mineral iron method was 0.44 mg Fe kg-1. The combination of neutralization and dilution of bicarbonate extract prevented CO2 interference during SI absorbance scanning. The performance of these methods indicated their suitability for sediment P and Fe monitoring of the Lagos Lagoon system.

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April 2016
5 Reads