Publications by authors named "Melissa Jia Bao Fong"

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Catalytic pyrolysis of Chlorella vulgaris: Kinetic and thermodynamic analysis.

Bioresour Technol 2019 Oct 22;289:121689. Epub 2019 Jun 22.

Department of Chemical Engineering, Faculty of Engineering and Science, Curtin University Malaysia, CDT 250, 98009 Miri Sarawak, Malaysia. Electronic address:

In the present study, catalytic pyrolysis of Chlorella vulgaris biomass was conducted to analyse the kinetic and thermodynamic performances through thermogravimetric approach. HZSM-5 zeolite, limestone (LS), bifunctional HZSM-5/LS were used as catalysts and the experiments were heated from 50 to 900 °C at heating rates of 10-100 °C/min. Iso-conversional model-free methods such as Flynn-Wall-Ozawa (FWO), Kissinger-Akahira-Sunose (KAS), Starink's, and Vyazovkin (V) were employed to evaluate the kinetic parameters meanwhile the thermodynamic parameters were determined by using FWO and KAS methods. The calculated E values of non-catalytic and catalytic pyrolysis of HZSM-5 zeolite, LS, and bifunctional HZSM-5/LS were determined to be in the range of 156.16-158.10 kJ/mol, 145.26-147.84 kJ/mol, 138.81-142.06 kJ/mol, and 133.26 kJ/mol respectively. The results have shown that catalytic pyrolysis with the presence of bifunctional HZSM-5/LS resulted to a lower average E and ΔH compared to HZSM-5, and LS which indicated less energy requirement in the process.
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http://dx.doi.org/10.1016/j.biortech.2019.121689DOI Listing
October 2019
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