Karl Gruber

Karl Gruber

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Karl Gruber

Karl Gruber

Publications by authors named "Karl Gruber"

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Zinc Substitution of Cobalt in Vitamin B : Zincobyric acid and Zincobalamin as Luminescent Structural B -Mimics.

Angew Chem Int Ed Engl 2019 Oct 4;58(41):14568-14572. Epub 2019 Sep 4.

Institute of Organic Chemistry and Center for Molecular Biosciences (CMBI), University of Innsbruck, 6020, Innsbruck, Austria.

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http://dx.doi.org/10.1002/anie.201908428DOI Listing
October 2019

The Hydrogenobyric Acid Structure Reveals the Corrin Ligand as an Entatic State Module Empowering B Cofactors for Catalysis.

Angew Chem Int Ed Engl 2019 Jul 26;58(31):10756-10760. Epub 2019 Jun 26.

Institute of Organic Chemistry and Center for Molecular Biosciences, University of Innsbruck, 6020, Innsbruck, Austria.

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http://dx.doi.org/10.1002/anie.201904713DOI Listing
July 2019

Chemoenzymatic Total Synthesis of Deoxy-, epi-, and Podophyllotoxin and a Biocatalytic Kinetic Resolution of Dibenzylbutyrolactones.

Angew Chem Int Ed Engl 2019 Jun 8;58(24):8226-8230. Epub 2019 May 8.

Institute of Chemistry, Organic and Bioorganic Chemistry, University of Graz, Heinrichstrasse 28/II, 8010, Graz, Austria.

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http://dx.doi.org/10.1002/anie.201900926DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6563474PMC
June 2019

Evolving the Promiscuity of Elizabethkingia meningoseptica Oleate Hydratase for the Regio- and Stereoselective Hydration of Oleic Acid Derivatives.

Angew Chem Int Ed Engl 2019 May 17;58(22):7480-7484. Epub 2019 Apr 17.

Institute of Molecular Biotechnology, Graz University of Technology, NAWI Graz, BioTechMed Graz, Petersgasse 14, 8010, Graz, Austria.

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http://dx.doi.org/10.1002/anie.201901462DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6563698PMC
May 2019

Structure and Catalytic Mechanism of a Bacterial Friedel-Crafts Acylase.

Chembiochem 2019 01 26;20(1):88-95. Epub 2018 Nov 26.

Austrian Centre of Industrial Biotechnology (ACIB), Petersgasse 14, 8010, Graz, Austria.

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http://doi.wiley.com/10.1002/cbic.201800462
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http://dx.doi.org/10.1002/cbic.201800462DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6392133PMC
January 2019

Oxidative cyclization of -methyl-dopa by a fungal flavoenzyme of the amine oxidase family.

J Biol Chem 2018 11 7;293(44):17021-17032. Epub 2018 Sep 7.

From the Institutes of Biochemistry, Graz University of Technology, Petersgasse 12/II, 8010 Graz,

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http://dx.doi.org/10.1074/jbc.RA118.004227DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6222107PMC
November 2018

Australia tackles HTLV-1.

Authors:
Karl Gruber

Lancet Infect Dis 2018 10;18(10):1073-1074

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http://dx.doi.org/10.1016/S1473-3099(18)30561-9DOI Listing
October 2018

Asymmetric Reductive Carbocyclization Using Engineered Ene Reductases.

Angew Chem Int Ed Engl 2018 06 14;57(24):7240-7244. Epub 2018 May 14.

Institute of Organic Chemistry, Graz University of Technology, Stremayrgasse 9, 8010, Graz, Austria.

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http://dx.doi.org/10.1002/anie.201802962DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6033016PMC
June 2018

Identification of Key Residues for Enzymatic Carboxylate Reduction.

Front Microbiol 2018 19;9:250. Epub 2018 Feb 19.

Institute of Molecular Biotechnology, Graz University of Technology, NAWI Graz, Graz, Austria.

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http://dx.doi.org/10.3389/fmicb.2018.00250DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5826065PMC
February 2018

Genetic basis for response to cancer immunotherapy.

Authors:
Karl Gruber

Lancet Oncol 2017 09 17;18(9):e521. Epub 2017 Aug 17.

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http://dx.doi.org/10.1016/S1470-2045(17)30627-7DOI Listing
September 2017

Polyester hydrolysis is enhanced by a truncated esterase: Less is more.

Biotechnol J 2017 Aug 11;12(8). Epub 2016 Oct 11.

Institute of Environmental Biotechnology, University of Natural Resources and Life Science (BOKU), Tulln an der Donau, Austria.

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http://dx.doi.org/10.1002/biot.201600450DOI Listing
August 2017

Structure, biochemical and kinetic properties of recombinant Pst2p from Saccharomyces cerevisiae, a FMN-dependent NAD(P)H:quinone oxidoreductase.

Biochim Biophys Acta Proteins Proteom 2017 Aug 10;1865(8):1046-1056. Epub 2017 May 10.

Institute of Biochemistry, Graz University of Technology, Petersgasse 12/2, 8010 Graz, Austria. Electronic address:

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http://dx.doi.org/10.1016/j.bbapap.2017.05.005DOI Listing
August 2017

Biocatalytic Friedel-Crafts Acylation and Fries Reaction.

Angew Chem Int Ed Engl 2017 06 23;56(26):7615-7619. Epub 2017 May 23.

ACIB GmbH, Petersgasse 14, 8010, Graz, Austria.

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http://dx.doi.org/10.1002/anie.201703270DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5488191PMC
June 2017

Clinical devices and services: Repair shops.

Nature 2017 05;545(7654):S21-S24

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http://dx.doi.org/10.1038/545S21aDOI Listing
May 2017

Agrobiodiversity: The living library.

Authors:
Karl Gruber

Nature 2017 04;544(7651):S8-S10

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http://dx.doi.org/10.1038/544S8aDOI Listing
April 2017

PpEst is a novel PBAT degrading polyesterase identified by proteomic screening of Pseudomonas pseudoalcaligenes.

Appl Microbiol Biotechnol 2017 Mar 21;101(6):2291-2303. Epub 2016 Nov 21.

Research Unit for Functional Proteomics and Metabolic Pathways, Institute of Pathology, Medical University of Graz, Stiftingtalstrasse 24, 8010, Graz, Austria.

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http://dx.doi.org/10.1007/s00253-016-7992-8DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5320007PMC
March 2017

Predicting zoonoses.

Authors:
Karl Gruber

Nat Ecol Evol 2017 Mar 23;1(4):98. Epub 2017 Mar 23.

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http://dx.doi.org/10.1038/s41559-017-0098DOI Listing
March 2017

Chlorophyll-Derived Yellow Phyllobilins of Higher Plants as Medium-Responsive Chiral Photoswitches.

Angew Chem Int Ed Engl 2016 12 28;55(51):15760-15765. Epub 2016 Nov 28.

Institute of Organic Chemistry and Centre of Molecular Biosciences, University of Innsbruck, 6020, Innsbruck, Austria.

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http://dx.doi.org/10.1002/anie.201609481DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5248603PMC
December 2016

Giving fruit a nutritional boost.

Authors:
Karl Gruber

Nat Plants 2016 12 2;2(12):16191. Epub 2016 Dec 2.

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http://dx.doi.org/10.1038/nplants.2016.191DOI Listing
December 2016

Curing multidrug-resistant tuberculosis: not all about the money.

Authors:
Karl Gruber

Lancet Respir Med 2016 11;4(11):870-871

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http://dx.doi.org/10.1016/S2213-2600(16)30335-6DOI Listing
November 2016

Structures of almond hydroxynitrile lyase isoenzyme 5 provide a rationale for the lack of oxidoreductase activity in flavin dependent HNLs.

J Biotechnol 2016 Oct 8;235:24-31. Epub 2016 Apr 8.

ACIB GmbH, Petersgasse 14, 8010 Graz, Austria; Institute of Molecular Biosciences, University of Graz, Humboldtstraße 50/3, 8010 Graz, Austria. Electronic address:

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http://dx.doi.org/10.1016/j.jbiotec.2016.04.013DOI Listing
October 2016

Total Synthesis, Structure, and Biological Activity of Adenosylrhodibalamin, the Non-Natural Rhodium Homologue of Coenzyme B12.

Angew Chem Int Ed Engl 2016 09 29;55(37):11281-6. Epub 2016 Jun 29.

Institut für Organische Chemie und Centrum für Molekulare Biowissenschaften (CMBI), Universität Innsbruck, 6020, Innsbruck, Austria.

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http://dx.doi.org/10.1002/anie.201603738DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5103170PMC
September 2016

Hydrolysis of synthetic polyesters by Clostridium botulinum esterases.

Biotechnol Bioeng 2016 May 20;113(5):1024-34. Epub 2015 Nov 20.

acib-Austrian Centre of Industrial Biotechnology, Konrad Lorenz Strasse 20, Tulln, 3430, Austria.

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http://dx.doi.org/10.1002/bit.25874DOI Listing
May 2016

Crystal structure of the Saccharomyces cerevisiae monoglyceride lipase Yju3p.

Biochim Biophys Acta 2016 May 9;1861(5):462-70. Epub 2016 Feb 9.

Institute of Molecular Biosciences, University of Graz, Humboldtstraße 50/3, 8010 Graz, Austria. Electronic address:

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http://dx.doi.org/10.1016/j.bbalip.2016.02.005DOI Listing
May 2016

Coenzyme B12 Repurposed for Photoregulation of Gene Expression.

Angew Chem Int Ed Engl 2016 05 24;55(19):5638-40. Epub 2016 Mar 24.

Institute of Organic Chemistry and Center for Molecular Biosciences (CMBI), University of Innsbruck, Innrain 80/82, 6020, Innsbruck, Austria.

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http://dx.doi.org/10.1002/anie.201601120DOI Listing
May 2016

The rocky road to destigmatising tuberculosis.

Authors:
Karl Gruber

Lancet Respir Med 2016 05 24;4(5):358. Epub 2016 Mar 24.

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http://dx.doi.org/10.1016/S2213-2600(16)30017-0DOI Listing
May 2016

The crystal structure of D-threonine aldolase from Alcaligenes xylosoxidans provides insight into a metal ion assisted PLP-dependent mechanism.

PLoS One 2015 17;10(4):e0124056. Epub 2015 Apr 17.

Austrian Centre of Industrial Biotechnology, Petersgasse 14, 8010, Graz, Austria; Institute of Molecular Biosciences, University of Graz, Humboldtstraße 50/3, 8010, Graz, Austria.

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http://journals.plos.org/plosone/article?id=10.1371/journal.pone.0124056PLOS
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4401734PMC
April 2016

Re-igniting the green revolution with wild crops.

Authors:
Karl Gruber

Nat Plants 2016 04 5;2:16048. Epub 2016 Apr 5.

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http://dx.doi.org/10.1038/nplants.2016.48DOI Listing
April 2016

Structural characterization of a Vatairea macrocarpa lectin in complex with a tumor-associated antigen: A new tool for cancer research.

Int J Biochem Cell Biol 2016 Mar 2;72:27-39. Epub 2016 Jan 2.

Departamento de Bioquímica e Biologia Molecular, Universidade Federal do Ceará, Av. Mister Hull s/n, Bloco 907, Box 6043, 60440-970, Fortaleza, Ceará, Brazil.

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http://dx.doi.org/10.1016/j.biocel.2015.12.016DOI Listing
March 2016

Substrate complexes of human dipeptidyl peptidase III reveal the mechanism of enzyme inhibition.

Sci Rep 2016 Mar 30;6:23787. Epub 2016 Mar 30.

Institute of Molecular Biosciences, University of Graz, Humboldtstraße 50/3, 8010 Graz, Austria.

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http://dx.doi.org/10.1038/srep23787DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4824452PMC
March 2016

Deep influence of soil microbes.

Authors:
Karl Gruber

Nat Plants 2015 Nov 23;1:15194. Epub 2015 Nov 23.

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http://dx.doi.org/10.1038/nplants.2015.194DOI Listing
November 2015

Structural and biochemical properties of LuxF from Photobacterium leiognathi.

Biochim Biophys Acta 2015 Oct 21;1854(10 Pt A):1466-75. Epub 2015 Jul 21.

Graz University of Technology, Institute of Biochemistry, Graz, Austria. Electronic address:

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http://dx.doi.org/10.1016/j.bbapap.2015.07.008DOI Listing
October 2015

Disparities in cancer mortality for elderly poor in the USA.

Authors:
Karl Gruber

Lancet Oncol 2015 Sep 6;16(9):e431. Epub 2015 Aug 6.

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http://dx.doi.org/10.1016/S1470-2045(15)00214-4DOI Listing
September 2015

Tubal ligation could reduce mortality in endometrial cancer.

Authors:
Karl Gruber

Lancet Oncol 2015 Aug 25;16(8):e380. Epub 2015 Jun 25.

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http://dx.doi.org/10.1016/S1470-2045(15)00117-5DOI Listing
August 2015

New genomic profiling tool to detect TB drug resistance.

Authors:
Karl Gruber

Lancet Respir Med 2015 Jul 23;3(7):512. Epub 2015 Jun 23.

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http://dx.doi.org/10.1016/S2213-2600(15)00248-9DOI Listing
July 2015

BRCA2 variant aerodigestive cancer risk.

Authors:
Karl Gruber

Lancet Oncol 2015 May 10;16(5):e204. Epub 2015 Apr 10.

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http://dx.doi.org/10.1016/S1470-2045(15)70173-7DOI Listing
May 2015

Regioselective Enzymatic β-Carboxylation of -Hydroxy- styrene Derivatives Catalyzed by Phenolic Acid Decarboxylases.

Adv Synth Catal 2015 May 2;357(8):1909-1918. Epub 2015 Apr 2.

Department of Chemistry, Organic & Bioorganic Chemistry, Heinrichstrasse 28, University of Graz 8010 Graz, Austria, ; phone: (+43)-316-380-5332 ; e-mail: or

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http://dx.doi.org/10.1002/adsc.201401028DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4498466PMC
May 2015

Long-lasting opioids and unintentional overdose.

Authors:
Karl Gruber

Lancet Oncol 2015 Apr 27;16(4):e159. Epub 2015 Feb 27.

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https://linkinghub.elsevier.com/retrieve/pii/S14702045157007
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http://dx.doi.org/10.1016/S1470-2045(15)70078-1DOI Listing
April 2015

Mutation patterns in lung cancer never-smokers.

Authors:
Karl Gruber

Lancet Oncol 2015 Apr 20;16(4):e163. Epub 2015 Mar 20.

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http://dx.doi.org/10.1016/S1470-2045(15)70132-4DOI Listing
April 2015

Moving towards a more precise treatment of diabetes.

Authors:
Karl Gruber

Lancet Diabetes Endocrinol 2015 Mar;3(3):171

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http://dx.doi.org/10.1016/S2213-8587(15)00010-8DOI Listing
March 2015

Structure of human dipeptidyl peptidase 10 (DPPY): a modulator of neuronal Kv4 channels.

Sci Rep 2015 Mar 5;5:8769. Epub 2015 Mar 5.

Institute of Molecular Biosciences, University of Graz, Humboldtstraße 50/3, A-8010 Graz, Austria.

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http://dx.doi.org/10.1038/srep08769DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350108PMC
March 2015

Coffee consumption and bladder cancer are linked, analysis shows.

Authors:
Karl Gruber

BMJ 2015 Mar 18;350:h1477. Epub 2015 Mar 18.

Perth.

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http://dx.doi.org/10.1136/bmj.h1477DOI Listing
March 2015

High-resolution structure of a new Tn antigen-binding lectin from Vatairea macrocarpa and a comparative analysis of Tn-binding legume lectins.

Int J Biochem Cell Biol 2015 Feb 12;59:103-10. Epub 2014 Dec 12.

Departamento de Bioquímica e Biologia Molecular, Universidade Federal do Ceará, Av. Mister Hull s/n, Bloco 907, Box 6043, 60440-970 Fortaleza, Ceará, Brazil. Electronic address:

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http://dx.doi.org/10.1016/j.biocel.2014.12.002DOI Listing
February 2015

Access sought to tuberculosis drug from nutraceutical company.

Authors:
Karl Gruber

Nat Med 2015 Feb 2;21(2):103. Epub 2015 Feb 2.

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http://dx.doi.org/10.1038/nm.3805DOI Listing
February 2015

Structure and stability of an unusual zinc-binding protein from Bacteroides thetaiotaomicron.

Biochim Biophys Acta 2014 Dec 28;1844(12):2298-305. Epub 2014 Sep 28.

Institute of Biochemistry, Graz University of Technology, A-8010 Graz, Austria. Electronic address:

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http://dx.doi.org/10.1016/j.bbapap.2014.08.008DOI Listing
December 2014

Cofactor Specificity Engineering of Streptococcus mutans NADH Oxidase 2 for NAD(P)(+) Regeneration in Biocatalytic Oxidations.

Comput Struct Biotechnol J 2014 26;9:e201402005. Epub 2014 Feb 26.

Austrian Centre of Industrial Biotechnology GmbH, c/o Institute of Molecular Biotechnology, Graz University of Technology, Petersgasse 14, 8010 Graz, Austria.

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http://ac.els-cdn.com/S2001037014600088/1-s2.0-S200103701460
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http://linkinghub.elsevier.com/retrieve/pii/S200103701460008
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http://dx.doi.org/10.5936/csbj.201402005DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3995211PMC
April 2014

Unique crystal structure of a novel surfactant protein from the foam nest of the frog Leptodactylus vastus.

Chembiochem 2014 Feb 17;15(3):393-8. Epub 2014 Jan 17.

Lab. de Ecologia Microbiana e Biotecnologia-LEMBiotech, Departamento de Biologia, Universidade Federal do Ceará, Av. Humberto Monte 2977, Campus do Pici, Bloco 909, Fortaleza, CE, 60455-000 (Brazil).

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http://dx.doi.org/10.1002/cbic.201300726DOI Listing
February 2014

Enzymatic aerobic alkene cleavage catalyzed by a Mn(3+) -dependent proteinase a homologue.

Chembiochem 2013 Dec 4;14(18):2427-30. Epub 2013 Nov 4.

Department of Chemistry, University of Graz, Heinrichstrasse 28, 8010 Graz (Austria).

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http://dx.doi.org/10.1002/cbic.201300601DOI Listing
December 2013

Biochemical and structural characterization of a novel bacterial manganese-dependent hydroxynitrile lyase.

FEBS J 2013 Nov 18;280(22):5815-28. Epub 2013 Sep 18.

Austrian Centre of Industrial Biotechnology GmbH, Graz, Austria; Gebouw voor Scheikunde, Technische Universiteit Delft, The Netherlands.

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http://dx.doi.org/10.1111/febs.12501DOI Listing
November 2013

Conformational plasticity and ligand binding of bacterial monoacylglycerol lipase.

J Biol Chem 2013 Oct 6;288(43):31093-104. Epub 2013 Sep 6.

From the Institute of Molecular Biosciences, University of Graz, Humboldtstrasse 50/3, A-8010 Graz, Austria.

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http://dx.doi.org/10.1074/jbc.M113.491415DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3829422PMC
October 2013

Distinct subspecies or phenotypic plasticity? Genetic and morphological differentiation of mountain honey bees in East Africa.

Ecol Evol 2013 Sep 6;3(10):3204-18. Epub 2013 Aug 6.

Evolutionsgenetik, Heinrich-Heine Universität Düsseldorf Düsseldorf, Germany.

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http://dx.doi.org/10.1002/ece3.711DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3797471PMC
September 2013

Targeting the substrate binding site of E. coli nitrile reductase QueF by modeling, substrate and enzyme engineering.

Chemistry 2013 May 17;19(22):7007-12. Epub 2013 Apr 17.

ACIB GmbH, c/o Institute of Organic Chemistry, Graz University of Technology, Stremayrgasse 9, 8010 Graz, Austria.

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http://dx.doi.org/10.1002/chem.201300163DOI Listing
May 2013

Asymmetric enzymatic hydration of hydroxystyrene derivatives.

Angew Chem Int Ed Engl 2013 Feb 17;52(8):2293-7. Epub 2013 Jan 17.

ACIB GmbH c/o Department of Chemistry, Organic & Bioorganic Chemistry, University of Graz, Heinrichstrasse 28, 8010 Graz, Austria.

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http://dx.doi.org/10.1002/anie.201207916DOI Listing
February 2013

Access to organometallic arylcobaltcorrins through radical synthesis: 4-ethylphenylcobalamin, a potential "antivitamin B(12)".

Angew Chem Int Ed Engl 2013 Feb 13;52(9):2606-10. Epub 2013 Feb 13.

Institute of Organic Chemistry and Centre of Molecular Biosciences, University of Innsbruck, Innrain 80/82, 6020 Innsbruck, Austria.

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http://doi.wiley.com/10.1002/anie.201209651
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http://dx.doi.org/10.1002/anie.201209651DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3843227PMC
February 2013

Europe gives gene therapy the green light.

Authors:
Karl Gruber

Lancet 2012 Nov;380(9855):e10

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http://dx.doi.org/10.1016/s0140-6736(12)61992-8DOI Listing
November 2012

Profile: German centre breathes new life into lung research.

Lancet 2012 Nov;380(9856):1806

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http://dx.doi.org/10.1016/s0140-6736(12)62013-3DOI Listing
November 2012

Can electromagnetic fields influence the structure and enzymatic digest of proteins? A critical evaluation of microwave-assisted proteomics protocols.

J Proteomics 2012 Oct 6;75(18):5533-43. Epub 2012 Aug 6.

Christian Doppler Laboratory for Microwave Chemistry (CDLMC) and Institute of Chemistry, Karl-Franzens-University Graz, Heinrichstrasse 28/I, A-8010 Graz, Austria.

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http://linkinghub.elsevier.com/retrieve/pii/S187439191200573
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http://dx.doi.org/10.1016/j.jprot.2012.07.043DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3484400PMC
October 2012

Inverting the regioselectivity of the berberine bridge enzyme by employing customized fluorine-containing substrates.

Chemistry 2012 Oct 7;18(41):13173-9. Epub 2012 Sep 7.

Department of Chemistry, Organic and Bioorganic Chemistry, University of Graz, Heinrichstrasse 28, 8010 Graz, Austria.

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http://doi.wiley.com/10.1002/chem.201201895
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http://dx.doi.org/10.1002/chem.201201895DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3533790PMC
October 2012

Structural and functional characterization of NikO, an enolpyruvyl transferase essential in nikkomycin biosynthesis.

J Biol Chem 2012 Sep 18;287(37):31427-36. Epub 2012 Jul 18.

Institute of Molecular Biosciences, University of Graz, A-8010 Graz, Austria.

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http://dx.doi.org/10.1074/jbc.M112.352096DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3438971PMC
September 2012

Hydroxynitrile lyases with α/β-hydrolase fold: two enzymes with almost identical 3D structures but opposite enantioselectivities and different reaction mechanisms.

Chembiochem 2012 Sep 31;13(13):1932-9. Epub 2012 Jul 31.

Institute of Pharmaceutical Sciences, Albert-Ludwigs-University Freiburg, Albertstrasse 25, Freiburg, Germany.

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http://dx.doi.org/10.1002/cbic.201200239DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3444685PMC
September 2012