Jin-Quan Yu

Jin-Quan Yu

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Jin-Quan Yu

Publications by authors named "Jin-Quan Yu"

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Reversing conventional site-selectivity in C(sp)-H bond activation.

Nat Chem 2019 Jun 15;11(6):571-577. Epub 2019 Apr 15.

Department of Chemistry, Scripps Research, La Jolla, CA, USA.

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http://dx.doi.org/10.1038/s41557-019-0245-6DOI Listing
June 2019

Synthesis of β-Arylethenesulfonyl Fluoride via Pd-Catalyzed Nondirected C-H Alkenylation.

Org Lett 2019 Mar 20;21(5):1426-1429. Epub 2019 Feb 20.

State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis , Shanghai Institute of Or-ganic Chemistry , CAS 345 Lingling Road , Shanghai 200032 , P.R. China.

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http://dx.doi.org/10.1021/acs.orglett.9b00165DOI Listing
March 2019

Ligand-Promoted Non-Directed C-H Cyanation of Arenes.

Chemistry 2019 Feb 16;25(9):2199-2202. Epub 2019 Jan 16.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/chem.201805772DOI Listing
February 2019

Pd -Catalyzed Enantioselective C(sp )-H Activation/Cross-Coupling Reactions of Free Carboxylic Acids.

Angew Chem Int Ed Engl 2019 Feb 16;58(7):2134-2138. Epub 2019 Jan 16.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://doi.wiley.com/10.1002/anie.201813055
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http://dx.doi.org/10.1002/anie.201813055DOI Listing
February 2019

Sequential Functionalization of meta-C-H and ipso-C-O Bonds of Phenols.

J Am Chem Soc 2019 Feb 24;141(5):1903-1907. Epub 2019 Jan 24.

Department of Chemistry , The Scripps Research Institute , 10550 North Torrey Pines Road , La Jolla , California 92037 , United States.

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http://dx.doi.org/10.1021/jacs.8b13403DOI Listing
February 2019

Rh(III)-Catalyzed meta-C-H Alkenylation with Alkynes.

J Am Chem Soc 2019 Jan 28;141(1):76-79. Epub 2018 Dec 28.

Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering , Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University , Nanjing 210023 , China.

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http://dx.doi.org/10.1021/jacs.8b11038DOI Listing
January 2019

Remote Para-C-H Acetoxylation of Electron-Deficient Arenes.

Org Lett 2019 Jan 7;21(2):540-544. Epub 2019 Jan 7.

Department of Chemistry , The Scripps Research Institute , 10550 North Torrey Pines Road , La Jolla , California 92037 , United States.

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http://dx.doi.org/10.1021/acs.orglett.8b03871DOI Listing
January 2019

Overcoming the Limitations of γ- and δ-C-H Arylation of Amines through Ligand Development.

J Am Chem Soc 2018 Dec 14;140(51):17884-17894. Epub 2018 Dec 14.

Department of Chemistry , The Scripps Research Institute , 10550 North Torrey Pines Road , La Jolla , California 92037 , United States.

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http://pubs.acs.org/doi/10.1021/jacs.8b07109
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http://dx.doi.org/10.1021/jacs.8b07109DOI Listing
December 2018

Ligand-Enabled β-C(sp)-H Olefination of Free Carboxylic Acids.

J Am Chem Soc 2018 Aug 2;140(32):10363-10367. Epub 2018 Aug 2.

Department of Chemistry , The Scripps Research Institute , 10550 North Torrey Pines Road , La Jolla , California 92037 , United States.

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http://dx.doi.org/10.1021/jacs.8b06527DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6524951PMC
August 2018

Palladium Catalyzed -C-H Functionalization of Masked Aromatic Aldehydes.

ACS Catal 2018 Aug 5;8(8):7362-7367. Epub 2018 Jul 5.

Department of Chemistry, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037.

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http://dx.doi.org/10.1021/acscatal.8b01599DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6301045PMC
August 2018

Controlling Pd(IV) reductive elimination pathways enables Pd(II)-catalysed enantioselective C(sp)-H fluorination.

Nat Chem 2018 07 11;10(7):755-762. Epub 2018 Jun 11.

Department of Chemistry, The Scripps Research Institute, La Jolla, California, USA.

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http://dx.doi.org/10.1038/s41557-018-0048-1DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6289870PMC
July 2018

Enantioselective remote meta-C-H arylation and alkylation via a chiral transient mediator.

Nature 2018 06 18;558(7711):581-585. Epub 2018 Jun 18.

Department of Chemistry, The Scripps Research Institute, La Jolla, CA, USA.

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http://www.nature.com/articles/s41586-018-0220-1
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http://dx.doi.org/10.1038/s41586-018-0220-1DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6026055PMC
June 2018

Copper mediated C-H amination with oximes: en route to primary anilines.

Chem Sci 2018 Jun 14;9(23):5160-5164. Epub 2018 May 14.

Department of Chemistry , The Scripps Research Institute , 10550N. Torrey Pines Road , La Jolla , California 92037 , USA.

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http://dx.doi.org/10.1039/c8sc01256cDOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6001278PMC
June 2018

Pd(II)-Catalyzed Enantioselective C(sp)-H Arylation of Free Carboxylic Acids.

J Am Chem Soc 2018 05 17;140(21):6545-6549. Epub 2018 May 17.

Department of Chemistry , The Scripps Research Institute , 10550 N. Torrey Pines Road , La Jolla , California 92037 , United States.

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http://pubs.acs.org/doi/10.1021/jacs.8b03509
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http://dx.doi.org/10.1021/jacs.8b03509DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038808PMC
May 2018

Enantioselective γ-C(sp)-H Activation of Alkyl Amines via Pd(II)/Pd(0) Catalysis.

J Am Chem Soc 2018 04 11;140(16):5322-5325. Epub 2018 Apr 11.

Department of Chemistry , The Scripps Research Institute , 10550 North Torrey Pines Road , La Jolla , California 92037 , United States.

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http://dx.doi.org/10.1021/jacs.8b01094DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5927623PMC
April 2018

Remote C-H Activation of Various N-Heterocycles Using a Single Template.

Chemistry 2018 Mar 12;24(14):3434-3438. Epub 2018 Feb 12.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/chem.201800105DOI Listing
March 2018

Ligand-Enabled γ-C(sp)-H Activation of Ketones.

J Am Chem Soc 2018 03 2;140(10):3564-3568. Epub 2018 Mar 2.

Department of Chemistry , The Scripps Research Institute , 10550 N. Torrey Pines Road , La Jolla , California 92037 , United States.

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http://dx.doi.org/10.1021/jacs.8b01359DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5851877PMC
March 2018

Enantioselective C-H Arylation and Vinylation of Cyclobutyl Carboxylic Amides.

ACS Catal 2018 Mar 5;8(3):2577-2584. Epub 2018 Feb 5.

Department of Chemistry, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037.

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http://dx.doi.org/10.1021/acscatal.8b00069DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5844484PMC
March 2018

Enantioselective C(sp)‒H bond activation by chiral transition metal catalysts.

Science 2018 02;359(6377)

The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA.

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http://dx.doi.org/10.1126/science.aao4798DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5862070PMC
February 2018

The mechanism of directed Ni(ii)-catalyzed C-H iodination with molecular iodine.

Chem Sci 2018 Feb 28;9(5):1144-1154. Epub 2017 Nov 28.

Cherry L. Emerson Centre for Scientific Computation , Emory University , 1515 Dickey Drive , Atlanta , Georgia 30322 , USA . Email:

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http://dx.doi.org/10.1039/c7sc04604aDOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5883947PMC
February 2018

Ligand-enabled -C-H olefination of phenylacetic amides with unactivated alkenes.

Chem Sci 2018 Feb 8;9(5):1311-1316. Epub 2017 Dec 8.

State Key Laboratory of Organometallic Chemistry , Shanghai Institute of Organic Chemistry , Chinese Academy of Sciences , 345 LingLing Road , Shanghai 20032 , China.

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http://dx.doi.org/10.1039/c7sc04827kDOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5887099PMC
February 2018

Rapid Syntheses of Heteroaryl-Substituted Imidazo[1,5-a]indole and Pyrrolo[1,2-c]imidazole via Aerobic C2-H Functionalizations.

Org Lett 2018 01 19;20(1):284-287. Epub 2017 Dec 19.

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry , Shanghai 200032, China.

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http://dx.doi.org/10.1021/acs.orglett.7b03596DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5993056PMC
January 2018

Pd-Catalyzed Remote Meta-C-H Functionalization of Phenylacetic Acids Using a Pyridine Template.

Org Lett 2018 01 5;20(2):425-428. Epub 2018 Jan 5.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/acs.orglett.7b03336DOI Listing
January 2018

Dynamic Ligand Exchange as a Mechanistic Probe in Pd-Catalyzed Enantioselective C-H Functionalization Reactions Using Monoprotected Amino Acid Ligands.

J Am Chem Soc 2017 12 14;139(51):18500-18503. Epub 2017 Dec 14.

Department of Chemistry, The Scripps Research Institute , La Jolla, California 92037, United States.

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http://pubs.acs.org/doi/10.1021/jacs.7b11962
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http://dx.doi.org/10.1021/jacs.7b11962DOI Listing
December 2017

An Epoxide-Mediated Deprotection Method for Acidic Amide Auxiliary.

Org Lett 2017 11;19(21):5860-5863

Department of Chemistry, The Scripps Research Institute , 10550 N. Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/acs.orglett.7b02841DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5710756PMC
November 2017

Versatile Alkylation of (Hetero)Aryl Iodides with Ketones via β-C(sp)-H Activation.

J Am Chem Soc 2017 11 3;139(45):16080-16083. Epub 2017 Nov 3.

Department of Chemistry, The Scripps Research Institute , La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.7b09761DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5710734PMC
November 2017

Experimental-Computational Synergy for Selective Pd(II)-Catalyzed C-H Activation of Aryl and Alkyl Groups.

Acc Chem Res 2017 11 8;50(11):2853-2860. Epub 2017 Nov 8.

Department of Chemistry and Biochemistry, University of California , Los Angeles, California 90095, United States.

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http://dx.doi.org/10.1021/acs.accounts.7b00440DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5702942PMC
November 2017

Ligand-accelerated non-directed C-H functionalization of arenes.

Nature 2017 11;551(7681):489-493

Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.

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http://www.nature.com/doifinder/10.1038/nature24632
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http://dx.doi.org/10.1038/nature24632DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5726549PMC
November 2017

Methylene C(sp)-H Arylation of Aliphatic Ketones Using a Transient Directing Group.

ACS Catal 2017 Oct 13;7(10):6938-6941. Epub 2017 Sep 13.

Department of Chemistry, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037.

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http://dx.doi.org/10.1021/acscatal.7b02905DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5640319PMC
October 2017

Highly Versatile β-C(sp)-H Iodination of Ketones Using a Practical Auxiliary.

J Am Chem Soc 2017 09 29;139(36):12394-12397. Epub 2017 Aug 29.

Department of Chemistry, The Scripps Research Institute , 10550 N. Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.7b06851DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5710739PMC
September 2017

One-pot synthesis of imidazolinium salts via the ring opening of tetrahydrofuran.

Dalton Trans 2017 Sep;46(37):12430-12433

Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China.

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http://dx.doi.org/10.1039/c7dt02883kDOI Listing
September 2017

Practical Alkoxythiocarbonyl Auxiliaries for Iridium(I)-Catalyzed C-H Alkylation of Azacycles.

Angew Chem Int Ed Engl 2017 08 24;56(35):10530-10534. Epub 2017 Jul 24.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/anie.201704755DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5561469PMC
August 2017

Palladium(II)-Catalyzed Site-Selective C(sp )-H Alkynylation of Oligopeptides: A Linchpin Approach for Oligopeptide-Drug Conjugation.

Angew Chem Int Ed Engl 2017 08 7;56(36):10924-10927. Epub 2017 Aug 7.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/anie.201706367DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5572133PMC
August 2017

Experimental and Computational Development of a Conformationally Flexible Template for the meta-C-H Functionalization of Benzoic Acids.

J Am Chem Soc 2017 08 27;139(31):10702-10714. Epub 2017 Jul 27.

The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.7b03296DOI Listing
August 2017

meta-C-H Arylation and Alkylation of Benzylsulfonamide Enabled by a Palladium(II)/Isoquinoline Catalyst.

Angew Chem Int Ed Engl 2017 07 9;56(28):8183-8186. Epub 2017 Jun 9.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/anie.201704411DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5553125PMC
July 2017

A Role for Pd(IV) in Catalytic Enantioselective C-H Functionalization with Monoprotected Amino Acid Ligands under Mild Conditions.

J Am Chem Soc 2017 07 27;139(27):9238-9245. Epub 2017 Jun 27.

Department of Chemistry, The Scripps Research Institute , La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.7b03716DOI Listing
July 2017

Palladium-Catalyzed Transformations of Alkyl C-H Bonds.

Chem Rev 2017 Jul 2;117(13):8754-8786. Epub 2016 Dec 2.

Department of Chemistry, The Scripps Research Institute , 10550 N. Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/acs.chemrev.6b00622DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5516964PMC
July 2017

Ligand-Enabled Auxiliary-Free meta-C-H Arylation of Phenylacetic Acids.

Angew Chem Int Ed Engl 2017 06 9;56(24):6874-6877. Epub 2017 May 9.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/anie.201702686DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5535739PMC
June 2017

Ligand-Promoted Rhodium(III)-Catalyzed ortho-C-H Amination with Free Amines.

Angew Chem Int Ed Engl 2017 06 29;56(26):7449-7453. Epub 2017 May 29.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/anie.201703300DOI Listing
June 2017

The Origins of Dramatic Differences in Five-Membered vs Six-Membered Chelation of Pd(II) on Efficiency of C(sp)-H Bond Activation.

J Am Chem Soc 2017 06 19;139(25):8514-8521. Epub 2017 Jun 19.

Department of Chemistry and Biochemistry, University of California , Los Angeles, California 90095, United States.

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http://dx.doi.org/10.1021/jacs.7b01801DOI Listing
June 2017

Copper-Mediated Late-Stage Functionalization of Heterocycle-Containing Molecules.

Angew Chem Int Ed Engl 2017 05 10;56(19):5317-5321. Epub 2017 Apr 10.

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 LingLing Road, Shanghai, 200032, China.

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http://dx.doi.org/10.1002/anie.201611287DOI Listing
May 2017

Ligand-Promoted meta-C-H Functionalization of Benzylamines.

Angew Chem Int Ed Engl 2017 04 30;56(18):5125-5129. Epub 2017 Mar 30.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/anie.201701803DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5512280PMC
April 2017

Ligand-Enabled Pd(II)-Catalyzed Bromination and Iodination of C(sp)-H Bonds.

J Am Chem Soc 2017 04 13;139(16):5724-5727. Epub 2017 Apr 13.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.7b02196DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5535776PMC
April 2017

Pd(II)-Catalyzed Enantioselective C(sp)-H Borylation.

J Am Chem Soc 2017 03 23;139(9):3344-3347. Epub 2017 Feb 23.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.6b13389DOI Listing
March 2017

Remote site-selective C-H activation directed by a catalytic bifunctional template.

Nature 2017 03 8;543(7646):538-542. Epub 2017 Mar 8.

Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.

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http://dx.doi.org/10.1038/nature21418DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5477648PMC
March 2017

Ligand-Enabled β-C-H Arylation of α-Amino Acids Without Installing Exogenous Directing Groups.

Angew Chem Int Ed Engl 2017 02 3;56(6):1506-1509. Epub 2017 Jan 3.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/anie.201610580DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5302090PMC
February 2017

Ligand-Enabled Alkynylation of C(sp )-H Bonds with Palladium(II) Catalysts.

Angew Chem Int Ed Engl 2017 02 12;56(7):1873-1876. Epub 2017 Jan 12.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/anie.201610426DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5512278PMC
February 2017

Rh(III)-Catalyzed meta-C-H Olefination Directed by a Nitrile Template.

J Am Chem Soc 2017 02 3;139(6):2200-2203. Epub 2017 Feb 3.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.6b13269DOI Listing
February 2017

Enantioselective amine α-functionalization via palladium-catalysed C-H arylation of thioamides.

Nat Chem 2017 02 3;9(2):140-144. Epub 2016 Oct 3.

Department of Chemistry, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA.

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http://dx.doi.org/10.1038/nchem.2619DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347480PMC
February 2017

Identification of monodentate oxazoline as a ligand for copper-promoted -C-H hydroxylation and amination.

Chem Sci 2017 Feb 26;8(2):1469-1473. Epub 2016 Sep 26.

State Key Laboratory of Organometallic Chemistry , Shanghai Institute of Organic Chemistry , Shanghai 20032 , China . Email: ; Email:

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http://dx.doi.org/10.1039/c6sc03383kDOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5452263PMC
February 2017

Copper-Catalyzed Bromination of C(sp )-H Bonds Distal to Functional Groups.

Angew Chem Int Ed Engl 2017 01 29;56(1):306-309. Epub 2016 Nov 29.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/anie.201608210DOI Listing
January 2017

Ligand-Enabled meta-Selective C-H Arylation of Nosyl-Protected Phenethylamines, Benzylamines, and 2-Aryl Anilines.

J Am Chem Soc 2017 01 23;139(1):417-425. Epub 2016 Dec 23.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.6b11097DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5497681PMC
January 2017

Diverse ortho-C(sp)-H Functionalization of Benzaldehydes Using Transient Directing Groups.

J Am Chem Soc 2017 01 9;139(2):888-896. Epub 2017 Jan 9.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.6b11188DOI Listing
January 2017

Pd-Catalyzed γ-C(sp)-H Arylation of Free Amines Using a Transient Directing Group.

J Am Chem Soc 2016 11 1;138(44):14554-14557. Epub 2016 Nov 1.

Chemical Development, Bristol-Myers Squibb, 1 Squibb Drive, New Brunswick, New Jersey 08903, United States.

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http://dx.doi.org/10.1021/jacs.6b09653DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5535771PMC
November 2016

Ligand Promoted meta-C-H Chlorination of Anilines and Phenols.

J Am Chem Soc 2016 11 8;138(45):14876-14879. Epub 2016 Nov 8.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.6b11055DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5512287PMC
November 2016

Ligand-Promoted meta-C-H Amination and Alkynylation.

J Am Chem Soc 2016 Oct 13;138(42):14092-14099. Epub 2016 Oct 13.

Department of Chemistry, The Scripps Research Institute , 10550 N. Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.6b08942DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5513786PMC
October 2016

Application of a Palladium-Catalyzed C-H Functionalization/Indolization Method to Syntheses of cis-Trikentrin A and Herbindole B.

Angew Chem Int Ed Engl 2016 09 29;55(39):11824-8. Epub 2016 Aug 29.

Department of Chemistry, University of California, Berkeley, Berkeley, CA, 94720, USA.

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http://dx.doi.org/10.1002/anie.201605475DOI Listing
September 2016

Ligand-accelerated enantioselective methylene C(sp3)-H bond activation.

Science 2016 09;353(6303):1023-1027

The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA.

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http://dx.doi.org/10.1126/science.aaf4434DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5516954PMC
September 2016

A Simple and Versatile Amide Directing Group for C-H Functionalizations.

Angew Chem Int Ed Engl 2016 08 1;55(36):10578-99. Epub 2016 Aug 1.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 N. Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/anie.201600791DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5518755PMC
August 2016

Rapid Construction of a Benzo-Fused Indoxamycin Core Enabled by Site-Selective C-H Functionalizations.

Angew Chem Int Ed Engl 2016 07 20;55(29):8270-4. Epub 2016 May 20.

Frick Chemistry Laboratory, Department of Chemistry, Princeton University, Washington Road, Princeton, NJ, 08544, USA.

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http://dx.doi.org/10.1002/anie.201602024DOI Listing
July 2016

Ligand-Promoted Meta-C-H Arylation of Anilines, Phenols, and Heterocycles.

J Am Chem Soc 2016 07 19;138(29):9269-76. Epub 2016 Jul 19.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.6b04966DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5512281PMC
July 2016

Kinetic Resolution of Benzylamines via Palladium(II)-Catalyzed C-H Cross-Coupling.

J Am Chem Soc 2016 06 10;138(24):7796-800. Epub 2016 Jun 10.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.6b04660DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5516893PMC
June 2016

Ligand-Promoted C(sp(3) )-H Olefination en Route to Multi-functionalized Pyrazoles.

Chemistry 2016 05 15;22(21):7059-62. Epub 2016 Apr 15.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/chem.201600704DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4944759PMC
May 2016

Ligand-Promoted Rh(III)-Catalyzed Coupling of Aryl C-H Bonds with Arylboron Reagents.

J Org Chem 2016 Apr 7;81(8):3416-22. Epub 2016 Apr 7.

Department of Chemistry, The Scripps Research Institute , 10550 N. Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/acs.joc.6b00083DOI Listing
April 2016

N-Heterocyclic Carbene Ligand-Enabled C(sp(3))-H Arylation of Piperidine and Tetrahydropyran Derivatives.

Chemistry 2016 Mar 24;22(14):4748-52. Epub 2016 Feb 24.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/chem.201600191DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4805524PMC
March 2016

Ligand-Enabled Arylation of γ-C-H Bonds.

Angew Chem Int Ed Engl 2016 Mar 25;55(13):4317-21. Epub 2016 Feb 25.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/anie.201512020DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4821162PMC
March 2016

Ligand-Enabled γ-C(sp(3))-H Olefination of Amines: En Route to Pyrrolidines.

J Am Chem Soc 2016 Feb 4;138(6):2055-9. Epub 2016 Feb 4.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.5b13462DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4817546PMC
February 2016

Enantioselective C-H Olefination of α-Hydroxy and α-Amino Phenylacetic Acids by Kinetic Resolution.

Angew Chem Int Ed Engl 2016 Feb 22;55(8):2856-60. Epub 2016 Jan 22.

Department of Chemistry, The Scripps Research Institution, 10550 N. Torrey Pines Road, La Jolla, CA, 92037, USA.

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http://dx.doi.org/10.1002/anie.201510808DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4899946PMC
February 2016

Pd(II)-Catalyzed C3-Selective Arylation of Pyridine with (Hetero)arenes.

Org Lett 2016 Feb 2;18(4):744-7. Epub 2016 Feb 2.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/acs.orglett.5b03712DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4821414PMC
February 2016

Pd-Catalyzed α-Selective C-H Functionalization of Olefins: En Route to 4-Imino-β-Lactams.

J Am Chem Soc 2016 Feb 16;138(7):2146-9. Epub 2016 Feb 16.

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China.

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http://dx.doi.org/10.1021/jacs.5b13353DOI Listing
February 2016

Ligand-Promoted Borylation of C(sp(3))-H Bonds with Palladium(II) Catalysts.

Angew Chem Int Ed Engl 2016 Jan 27;55(2):785-9. Epub 2015 Nov 27.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA 92037 (USA).

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http://dx.doi.org/10.1002/anie.201509996DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4821169PMC
January 2016

Organic chemistry. Functionalization of C(sp3)-H bonds using a transient directing group.

Science 2016 Jan;351(6270):252-6

The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA.

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http://dx.doi.org/10.1126/science.aad7893DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4817545PMC
January 2016

β-C(sp(3))-H Arylation of α-Hydroxy Acid Derivatives Utilizing Amino Acid as a Directing Group.

Org Lett 2015 Dec 4;17(24):5966-9. Epub 2015 Dec 4.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/acs.orglett.5b02900DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4817547PMC
December 2015

Remote Meta-C-H Activation Using a Pyridine-Based Template: Achieving Site-Selectivity via the Recognition of Distance and Geometry.

ACS Cent Sci 2015 Oct 16;1(7):394-9. Epub 2015 Oct 16.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/acscentsci.5b00312DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4827496PMC
October 2015

Enantioselective ortho-C-H cross-coupling of diarylmethylamines with organoborons.

Angew Chem Int Ed Engl 2015 Sep 4;54(38):11143-6. Epub 2015 Aug 4.

Department of Chemistry, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, CA 92037 (USA).

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http://dx.doi.org/10.1002/anie.201505204DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4642891PMC
September 2015

Cu(II)-Mediated C(sp(2))-H Hydroxylation.

J Org Chem 2015 Sep 17;80(17):8843-8. Epub 2015 Aug 17.

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China.

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http://dx.doi.org/10.1021/acs.joc.5b01351DOI Listing
September 2015

Practical Pd(II)-Catalyzed C-H Alkylation with Epoxides: One-Step Syntheses of 3,4-Dihydroisocoumarins.

J Am Chem Soc 2015 Sep 19;137(34):10950-3. Epub 2015 Aug 19.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.5b07507DOI Listing
September 2015

Ligand-Enabled Meta-C-H Alkylation and Arylation Using a Modified Norbornene.

J Am Chem Soc 2015 Sep 3;137(36):11574-7. Epub 2015 Sep 3.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.5b08914DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4573956PMC
September 2015

α-Arylation of Saturated Azacycles and N-Methylamines via Palladium(II)-Catalyzed C(sp(3))-H Coupling.

J Am Chem Soc 2015 Sep 10;137(37):11876-9. Epub 2015 Sep 10.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.5b06740DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4822695PMC
September 2015

Monoselective o-C-H Functionalizations of Mandelic Acid and α-Phenylglycine.

J Am Chem Soc 2015 Aug 30;137(31):9877-84. Epub 2015 Jul 30.

Department of Chemistry, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.5b04324DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4538457PMC
August 2015

Ligand-Controlled Para-Selective C-H Arylation of Monosubstituted Arenes.

Org Lett 2015 Aug 23;17(15):3830-3. Epub 2015 Jul 23.

†State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.

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http://dx.doi.org/10.1021/acs.orglett.5b01802DOI Listing
August 2015

Mechanistic Details of Pd(II)-Catalyzed C-H Iodination with Molecular I2: Oxidative Addition vs Electrophilic Cleavage.

J Am Chem Soc 2015 Jul 14;137(28):9022-31. Epub 2015 Jul 14.

†Cherry L. Emerson Center for Scientific Computation, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States.

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http://dx.doi.org/10.1021/jacs.5b03410DOI Listing
July 2015

A combined IM-MS/DFT study on [Pd(MPAA)]-catalyzed enantioselective C-H activation: relay of chirality through a rigid framework.

Chemistry 2015 Jul 17;21(31):11180-8. Epub 2015 Jun 17.

Lab of Computational Chemistry and Drug Design, Key Laboratory of Chemical Genomics, Peking University Shenzhen Graduate School, Shenzhen 518055 (P.R. China).

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http://doi.wiley.com/10.1002/chem.201501123
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July 2015

Ligand-Enabled Stereoselective β-C(sp(3))-H Fluorination: Synthesis of Unnatural Enantiopure anti-β-Fluoro-α-amino Acids.

J Am Chem Soc 2015 Jun 27;137(22):7067-70. Epub 2015 May 27.

Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://pubs.acs.org/doi/10.1021/jacs.5b04088
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http://dx.doi.org/10.1021/jacs.5b04088DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4934178PMC
June 2015

Palladium(0)/PAr3 -Catalyzed Intermolecular Amination of C(sp(3) )H Bonds: Synthesis of β-Amino Acids.

Angew Chem Int Ed Engl 2015 May 14;54(22):6545-9. Epub 2015 Apr 14.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA 92037 (USA).

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http://doi.wiley.com/10.1002/anie.201502075
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http://dx.doi.org/10.1002/anie.201502075DOI Listing
May 2015

γ,δ,ε-C(sp(3))-H Functionalization through Directed Radical H-Abstraction.

J Am Chem Soc 2015 May 30;137(18):5871-4. Epub 2015 Apr 30.

†Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/jacs.5b02065DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4431913PMC
May 2015

Pd(II)-catalyzed C-H functionalizations directed by distal weakly coordinating functional groups.

J Am Chem Soc 2015 Apr 24;137(13):4391-7. Epub 2015 Mar 24.

Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/ja5126897DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4431596PMC
April 2015

Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes.

J Am Chem Soc 2015 Apr 2;137(14):4618-21. Epub 2015 Apr 2.

Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://pubs.acs.org/doi/10.1021/jacs.5b00890
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http://dx.doi.org/10.1021/jacs.5b00890DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4432906PMC
April 2015

Ligand-Accelerated -C-H Olefination of Phenylacetic Acids.

Organic Synth 2015;92:58-75. Epub 2015 Mar 12.

Department of Chemistry, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, CA 92037, USA.

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http://dx.doi.org/10.15227/orgsyn.092.0058DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4936495PMC
March 2015

Cu(II)-catalyzed coupling of aromatic C-H bonds with malonates.

Org Lett 2015 Mar 19;17(5):1228-31. Epub 2015 Feb 19.

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China.

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http://dx.doi.org/10.1021/acs.orglett.5b00193DOI Listing
March 2015

Ligand-enabled β-C-H arylation of α-amino acids using a simple and practical auxiliary.

J Am Chem Soc 2015 Mar 3;137(9):3338-51. Epub 2015 Mar 3.

Department of Chemistry, The Scripps Research Institute , 10550 N. Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/ja512690xDOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4432912PMC
March 2015

Rh(iii)-catalyzed C-H olefination of -pentafluoroaryl benzamides using air as the sole oxidant.

Chem Sci 2015 Mar 8;6(3):1923-1927. Epub 2015 Jan 8.

Department of Chemistry , The Scripps Research Institute , 10550 N. Torrey Pines Road , La Jolla , California 92037 , USA . Email:

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http://xlink.rsc.org/?DOI=C4SC03350G
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http://dx.doi.org/10.1039/c4sc03350gDOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5810239PMC
March 2015

Ligand-enabled meta-C-H activation using a transient mediator.

Nature 2015 Mar 9;519(7543):334-8. Epub 2015 Mar 9.

Department of Chemistry, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA.

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http://dx.doi.org/10.1038/nature14214DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4368492PMC
March 2015

Palladium(II)-catalyzed highly enantioselective C-H arylation of cyclopropylmethylamines.

J Am Chem Soc 2015 Feb 27;137(5):2042-6. Epub 2015 Jan 27.

Department of Chemistry, The Scripps Research Institute , 10550 North Torrey Pines Road, La Jolla, California 92037, United States.

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http://dx.doi.org/10.1021/ja512529eDOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4433166PMC
February 2015

Ligand-promoted ortho-C-H amination with Pd catalysts.

Angew Chem Int Ed Engl 2015 Feb 16;54(8):2497-500. Epub 2015 Jan 16.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA 92037 (USA).

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http://dx.doi.org/10.1002/anie.201408651DOI Listing
February 2015

Orchestrated triple C-H activation reactions using two directing groups: rapid assembly of complex pyrazoles.

Angew Chem Int Ed Engl 2015 Feb 16;54(8):2501-4. Epub 2015 Jan 16.

Department of Chemistry, The Scripps Research Institute (TSRI), 10550 North Torrey Pines Road, La Jolla, CA 92037 (USA).

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http://doi.wiley.com/10.1002/anie.201410462
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http://dx.doi.org/10.1002/anie.201410462DOI Listing
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4426881PMC
February 2015